Preparation and use of salts of 6,8-bis(amidiniumthio)octanoic acid

6,8-Bis(amidiniumthio)octanoic acid salts for formula CH2(SC(NH2)2X)-CH2-CH(SC(NH2)2Y)-CH 2-CH2-CH2-CH2-COOR (III) are new. R = H or 1-3C alkyl; X, Y = anions of a mineral acid, alkyl- or arylsulphonic acid, or carboxylic acid. Also claimed is the use of (III) for the synthesis of racemic 6,8-dimerc...

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Hauptverfasser: BEISSWENGER, THOMAS, GEWALD, RAINER, RAUTENBERG, STEPHAN, OLBRICH, ALFRED DR, KLENK, HERBERT, BETHGE, HORST, HUTHMACHER, KLAUS, HUEBNER, FRANK, MOELLER, ROLAND, SATOR, GERHARD
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Sprache:eng
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Zusammenfassung:6,8-Bis(amidiniumthio)octanoic acid salts for formula CH2(SC(NH2)2X)-CH2-CH(SC(NH2)2Y)-CH 2-CH2-CH2-CH2-COOR (III) are new. R = H or 1-3C alkyl; X, Y = anions of a mineral acid, alkyl- or arylsulphonic acid, or carboxylic acid. Also claimed is the use of (III) for the synthesis of racemic 6,8-dimercaptooctanoic acid, (+)-6,8-dihydrolipoic acid, (-)-6,8-dihydrolipoic acid, racemic alpha -lipoic acid, (+)- alpha -lipoic acid or (-)- alpha -lipoic acid.