Preparation of alkylated phenols

A lubricating additive comprises a phenol which has been alkylated with an olefin polymer in the presence of a montmorillonite clay catalyst having a surface area of at least 100 square metres per gram, further treated with P2S5-treated polybutene and the resultant product reacted with Ba(OH)2 and C...

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Bibliographische Detailangaben
Hauptverfasser: WILKS GORDON NOEL, WINWARD ANTONY
Format: Patent
Sprache:eng
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Beschreibung
Zusammenfassung:A lubricating additive comprises a phenol which has been alkylated with an olefin polymer in the presence of a montmorillonite clay catalyst having a surface area of at least 100 square metres per gram, further treated with P2S5-treated polybutene and the resultant product reacted with Ba(OH)2 and CO2.ALSO:Phenols are alkylated by reacting the phenol with an olefin polymer in the presence of a montmorillonite clay catalyst having a surface area of at least 100 square metres/gram. The clay may be activated by treatment with acid, particularly when olefin polymers of wide boiling range are used. The preferred olefins contain 7-12 carbon atoms. Examples describe the alkylation of phenol itself. Lubricant additives may be prepared by treating the alkylated phenol with barium oxide and then with sulphur.