Vegetable oil polyol with suspension chain removed and preparation method and application thereof

A vegetable polyol preparation method comprises of the following steps: [i] reacting vegetable oil with ethylene and a Grubbs Catalyst 2nd Generation in a reaction kettle to obtain vegetable oil with a suspension chain removed, [ii] reacting the vegetable oil obtained in step [i] with N-bromosuccini...

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Bibliographische Detailangaben
Hauptverfasser:	Kai Guo, Changzhu Chen, Wei He, Yiping Huang, Ren Ma, Zheng Fang, Fujian Liu, Kequan Chen
Format:	Patent
Sprache:	eng
Schlagworte:	ACYCLIC OR CARBOCYCLIC COMPOUNDS ADHESIVES ANIMAL AND VEGETABLE OILS, FATS, FATTY SUBSTANCES AND WAXES CANDLES CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY CHEMICAL PAINT OR INK REMOVERS CHEMISTRY COATING COMPOSITIONS, e.g. PAINTS, VARNISHES ORLACQUERS COMPOSITIONS BASED THEREON CORRECTING FLUIDS DETERGENTS DYES FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS,OILS, OR FATTY ACIDS OBTAINED THEREFROM FATTY ACIDS FROM FATS, OILS OR WAXES FATTY ACIDS THEREFROM FILLING PASTES INKS MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONSONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS METALLURGY MISCELLANEOUS APPLICATIONS OF MATERIALS MISCELLANEOUS COMPOSITIONS NATURAL RESINS ORGANIC CHEMISTRY ORGANIC MACROMOLECULAR COMPOUNDS PAINTS PASTES OR SOLIDS FOR COLOURING OR PRINTING PERFORMING OPERATIONS PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL POLISHES THEIR PREPARATION OR CHEMICAL WORKING-UP THEIR RELEVANT APPARATUS TRANSPORTING USE OF MATERIALS THEREFOR WOODSTAINS
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Beschreibung
Zusammenfassung:	A vegetable polyol preparation method comprises of the following steps: [i] reacting vegetable oil with ethylene and a Grubbs Catalyst 2nd Generation in a reaction kettle to obtain vegetable oil with a suspension chain removed, [ii] reacting the vegetable oil obtained in step [i] with N-bromosuccinimide and dimethyl sulfoxide in the reaction kettle to obtain a product (a); [iii] reacting the product (a) obtained in step [ii] with diethyl ether and 1,8-diazabicyclo[5.4.0]undec-7-ene in the reaction kettle to obtain a product (b); [iv] using the product (b) obtained in step [iii] as an ingredient I, using a mixed solution of aldehyde and toluene as an ingredient II, respectively and simultaneously pumping the ingredient I and the ingredient II into a first micromixer of a micro channel modular reaction device for mixing, and pumping the mixture into a first microreactor for a reaction after mixing to obtain a vegetable oil polyol (c); and [v] carrying out a hydrogenation reaction on the vegetable oil polyol (c) obtained in step [iv] with a Pd/C catalyst and hydrogen in the reaction kettle to obtain the vegetable oil polyol with the suspension chain removed. Also disclosed is a vegetable oil polyol prepared using the said method; use of the vegetable oil polyol in a polyurethane elastomer and a polyurethane coating.