Improvements in relation to security printing

An article comprising a substrate which carries a doped tin oxide wherein less than 50 mol% of the tin atoms in the tin oxide are substituted with a dopant element, e.g. antimony, tungsten, fluorine or phosphorus. The doped tin oxides may be used as invisible but IR-active pigments for confirming ge...

Ausführliche Beschreibung

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Bibliographische Detailangaben
Hauptverfasser: David Malcolm Lewis, Dieter Guhl
Format: Patent
Sprache:eng
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Beschreibung
Zusammenfassung:An article comprising a substrate which carries a doped tin oxide wherein less than 50 mol% of the tin atoms in the tin oxide are substituted with a dopant element, e.g. antimony, tungsten, fluorine or phosphorus. The doped tin oxides may be used as invisible but IR-active pigments for confirming genuineness of an article or for assessing its quality. A genuine article may be determined by measuring the absorption of the article, which may be non-uniform, at two different wavelengths in the infra-red range and calculating their ratio. The quality is assessed by comparing the IR absorption with a standard. The article may be a banknote, which has either the doped tin oxide (e.g. cassiterite, SnO2) distributed throughout the substrate or the doped tin oxide is applied as an ink composition. The ink compositions may have tin oxide with 5 20 mol% antimony or with 1.5 mol% fluorine. The banknote may contain a covert security image or hidden coating. The difference in colour dE between substrate with doped tin oxide and without it may be less than 2.