PROCESS FOR THE PRODUCTION OF ANTHRAQUINONE DERIVATIVES CHLORINATED IN alpha-POSITIONS

1,204,420. Anthraquinone compounds. SANDOZ Ltd. 2 Aug., 1968 [11 Aug., 1967; 14 Sept., 1967; 8 March, 1968; 6 June, 1968], No. 35159/68. Heading C2C. [Also in Division C4] Boric acid or boron fluoride complexes of 1,4- dihydroxy anthraquinones are chlorinated in the α-position with a mixture of oleu...

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Hauptverfasser: KARL ULRICH STEINER, WOLFGANG SCHOENAUER
Format: Patent
Sprache:eng
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Zusammenfassung:1,204,420. Anthraquinone compounds. SANDOZ Ltd. 2 Aug., 1968 [11 Aug., 1967; 14 Sept., 1967; 8 March, 1968; 6 June, 1968], No. 35159/68. Heading C2C. [Also in Division C4] Boric acid or boron fluoride complexes of 1,4- dihydroxy anthraquinones are chlorinated in the α-position with a mixture of oleum and chlorosulphonic acid, thionyl chloride or sulphuryl chloride in the presence of a halogenation catalyst and in the absence of substantial quantities of gaseous chlorine. The catalyst is preferably iodine or a compound which yields iodine under the reaction conditions.