Process for the after-treatment of polypivalolactone articles

Compositions for moulding which may be annealed without deformation other than shrinkage comprise a homo or copolymer of pivalolactone and a nucleating agent. The pivalolactone may be copolymerized with up to 25 mole per cent of b -propiolactone, a ,a -diethyl -b -propiolactone, or a -methyl, a -eth...

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Hauptverfasser: SELMAN JAN, OOSTERHOF HENDRICUS ANTHONIUS
Format: Patent
Sprache:eng
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Zusammenfassung:Compositions for moulding which may be annealed without deformation other than shrinkage comprise a homo or copolymer of pivalolactone and a nucleating agent. The pivalolactone may be copolymerized with up to 25 mole per cent of b -propiolactone, a ,a -diethyl -b -propiolactone, or a -methyl, a -ethyl, b -propiolactone, polyamides or other polyesters. The nucleating agent which is present in 0.01 to 2% by weight may be silica, boron nitride, a binary compound of formula MX where M = an alkali metal and X = a halogen other than fluoride, or a neutral salt of a mono-, di- or trivalent metal and an organic acid with a carboxy, sulpho, sulphino, phosphono or phosphinico group attached to an aromatic carbon atom. Many examples of nucleating agents are given.