PROCEDE ELECTROCHIMIQUE DE PREPARATION DE DERIVES ORGANIQUES TRIFLUORO (OU CHLORODIFLUORO OU DICHLOROFLUORO) METHYLES
L'INVENTION CONCERNE LA PREPARATION DE DERIVES ORGANIQUES TRIFLUORO (OU CHLORODIFLUORO OU DICHLOROFLUORO) METHYLES.LE PROCEDE SELON L'INVENTION CONSISTE A REDUIRE PAR VOIE ELECTROCHIMIQUE UN COMPOSE C1FC-BR (X0,1 OU 2) EN PRESENCE D'UN SUBSTRAT ELECTROPHILE NON ELECTROACTIF ET D'...
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Format: | Patent |
Sprache: | fre |
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Zusammenfassung: | L'INVENTION CONCERNE LA PREPARATION DE DERIVES ORGANIQUES TRIFLUORO (OU CHLORODIFLUORO OU DICHLOROFLUORO) METHYLES.LE PROCEDE SELON L'INVENTION CONSISTE A REDUIRE PAR VOIE ELECTROCHIMIQUE UN COMPOSE C1FC-BR (X0,1 OU 2) EN PRESENCE D'UN SUBSTRAT ELECTROPHILE NON ELECTROACTIF ET D'UN ELECTROLYTE SUPPORT DANS UN SOLVANT APROTIQUE.
A process for the preparation of an organic trihalomethyl derivative comprising electrolytically reducing a compound of the formula: ClxF3-xC-Br in which x is equal to 0, 1 or 2, in a reaction medium also containing an electrophilic substrate which is void of electrochemical activity at the reduction potential of said compound, and a support electrolyte in an aprotic solvent for a time and at a temperature sufficient to form the desired organic trihalomethyl derivative. |
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