3-Substd. 2,6-dinitro 4-trifluoromethyl anilines - useful as fungicides and herbicides

New 2,6-dinitro-4-trifluoromethylaniline derivs. are of formula (I): In the formula Q is NHCN, N3, SCN, SACN or SCH2COOMe; A is 1-4C alkylene, R1 is H, 1-5C non-tert. alkyl, 3-4C alkenyl, 2-3C chloroalkyl, 3-4C chloroalkenyl or cyclopropylmethyl, R2 is 1-7C non-tert. alkyl, 3-4C alkenyl, phenyl, 2-3...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
1. Verfasser: JAMES RICHARD BECK ET JOSEPH ANDREW YAHNER
Format: Patent
Sprache:eng ; fre
Schlagworte:
Online-Zugang:Volltext bestellen
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:New 2,6-dinitro-4-trifluoromethylaniline derivs. are of formula (I): In the formula Q is NHCN, N3, SCN, SACN or SCH2COOMe; A is 1-4C alkylene, R1 is H, 1-5C non-tert. alkyl, 3-4C alkenyl, 2-3C chloroalkyl, 3-4C chloroalkenyl or cyclopropylmethyl, R2 is 1-7C non-tert. alkyl, 3-4C alkenyl, phenyl, 2-3C chloroalkyl, 3-4C chloroalkenyl, chlorophenyl, cyclopropylmethyl, 3-4C alkynyl, tetrahydrofuryl-1-3C-alkyl, N-methyl-2-propionamide (sic) or N(R3)2, with the proviso that R2 can only be N(R3)2 when R1 H; R3 is 1-3C alkyl). The triethylamine, pyridine and alkali metal salts of (I) when Q = NHCN are also claimed. Cpds. (I) are useful as (a) fungicides, e.g. for control of mildew (Plasmopara) on grape vines, and (b) as herbicides. In an example, the triethylamine salt of 3-cyanoamino-2,6-dinitro-N-(3-pentyl)-4-trifluoromethylaniline is prepd. by reacting 3-chloro-2,6-dinitro-N-(3-pentyl)-4-trifluoromethylaniline with cyanamide in the presence of triethylamine.