RUTENIUM PHOTOCATALISERS (II) AND IMINAS PHOTOCATALYTIC SYNTHESIS (Machine-translation by Google Translate, not legally binding)

Ruthenium (II) photocatalysts and photocatalytic synthesis of imines. Ruthenium (II) photocatalysts of formula (M+n Xn- are described, in which Xn - is an anion and M+ is a cationic complex of formula (Ia): {IMAGE} comprising an 8-anylsulfonamidoquinoline ligand, as well as its procedure for obtaini...

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Hauptverfasser:	Hidalgo Zorrilla, Jairo, Jalón Sotés, Félix Angel, Manzano Manrique, Blanca Rosa, Espino Ordóñez, Gustavo, Carbayo Martín, Arancha, Vaquero Gutiérrez, Mónica, Yagüe Izquierdo, Cristina, Echevarría Poza, Igor
Format:	Patent
Sprache:	eng ; spa
Schlagworte:	ACYCLIC OR CARBOCYCLIC COMPOUNDS ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY CHEMISTRY HETEROCYCLIC COMPOUNDS METALLURGY ORGANIC CHEMISTRY PERFORMING OPERATIONS PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL THEIR RELEVANT APPARATUS TRANSPORTING
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Beschreibung
Zusammenfassung:	Ruthenium (II) photocatalysts and photocatalytic synthesis of imines. Ruthenium (II) photocatalysts of formula (M+n Xn- are described, in which Xn - is an anion and M+ is a cationic complex of formula (Ia): {IMAGE} comprising an 8-anylsulfonamidoquinoline ligand, as well as its procedure for obtaining it. The use of said Ruthenium (II) photocatalysts in the synthesis of imines by photooxidation of amines in the presence of oxygen and by using visible light. (Machine-translation by Google Translate, not legally binding) Fotocatalizadores de rutenio (II) y síntesis fotocatalítica de iminas. Se describe fotocatalizadores de rutenio (II) de fórmula (M+nXn-, en el que Xn- es un anión y M+ es un complejo catiónico de fórmula (Ia):{IMAGEN} que comprenden un ligando 8-anilsulfonamidoquinolina, así como su procedimiento de obtención. También se describe el uso de dichos fotocatalizadores de rutenio(II) en la síntesis de iminas mediante fotooxidación de aminas en presencia de oxígeno y mediante la utilización de luz visible.