METHOD FOR PRODUCING POROUS ARTICLES FROM ULTRA HIGH MOLECULAR WEIGHT POLYETHYLENE
Ultra high molecular weight polyethylene (UHMWPE) polymers that have an average molecular weight of at least 2,000,000 g/mol and an enthalpy of at least 190 J/g is provided. The UHMWPE polymer may include at least one comonomer. The UHMWPE polymer is used to form a membrane, that, when expanded, has...
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Zusammenfassung: | Ultra high molecular weight polyethylene (UHMWPE) polymers that have an average molecular weight of at least 2,000,000 g/mol and an enthalpy of at least 190 J/g is provided. The UHMWPE polymer may include at least one comonomer. The UHMWPE polymer is used to form a membrane, that, when expanded, has a node and fibril structure. The UHMWPE membrane has an endotherm of about 150°C associated with the fibrils in the membrane. The membrane has a percent porosity of at least 60% and a bubble point of a bubble point of 138 kPa or less. Additionally, the UHMWPE membrane has a thickness less than 1 mm. An UHMWPE membrane may be formed by lubricating the UHMWPE polymer, subjecting the lubricated polymer to pressure at a temperature below the melting point of the UHMWPE polymer to form a tape, and expanding the tape at a temperature both below and above the melting temperature of the UHMWPE polymer. |
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