DUAL METALLOCENE BIMODAL HDPE RESINS WITH IMPROVED STRESS CRACK RESISTANCE

Ethylene-based polymers having a density from 0.94 to 0.96 g/cm3, a Mn from 5,000 to 14,000 g/mol, a ratio of Mw/Mn from 18 to 40, and at least one of a PENT value at 2.4 MPa of at least 11,500 hr and/or a W90 from 7.5 to 15 wt. % are disclosed. Additional ethylene polymers can have the same density...

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Hauptverfasser: SUKHADIA, Ashish, M, YU, Youlu, PRAETORIUS, Jeremy, M, SOULES, David, A, ROHATGI, Vivek, YANG, Qing
Format: Patent
Sprache:eng ; fre ; ger
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Zusammenfassung:Ethylene-based polymers having a density from 0.94 to 0.96 g/cm3, a Mn from 5,000 to 14,000 g/mol, a ratio of Mw/Mn from 18 to 40, and at least one of a PENT value at 2.4 MPa of at least 11,500 hr and/or a W90 from 7.5 to 15 wt. % are disclosed. Additional ethylene polymers can have the same density, Mn, and Mw/Mn values, as well as a relaxation time from 0.5 to 3.5 sec, a CY-a parameter from 0.48 to 0.68, a HLMI from 5 to 11 g/10 min, a viscosity at HLMI from 3,000 to 7,500 Pa-sec, and a higher molecular weight component (HMW) and a lower molecular weight (LMW) component, in which a ratio of the number of SCBs at Mp of the HMW component to the number of SCBs at Mp of the LMW component is from 3.5 to 8.