METHOD OF RECOVERING A HYDROGEN-ENRICHED PRODUCT AND CO2 IN A HYDROGEN PRODUCTION UNIT

A process and apparatus for producing a hydrogen-enriched product and recovering CO2 from an effluent stream from a hydrogen production unit are described. The effluent from the hydrogen production unit, which comprises a mixture of gases comprising hydrogen, carbon dioxide, water, and at least one of methane, carbon monoxide, nitrogen, and argon, is sent to a PSA system that produces at least two product streams for separation. The PSA system that produces at least two product streams separates the gas mixture into a high-pressure hydrogen stream enriched in hydrogen, optionally a second gas stream containing the majority of the impurities, and a low-pressure tail gas stream enriched in CO2 and some impurities. The CO2-rich tail gas stream is compressed and sent to a CO2 recovery unit, where a CO2-enriched stream is recovered. The CO2-depleted overhead gas stream is recycled to the PSA system that produces at least two product streams.