HYDROCARBYL-MODIFIED METHYLALUMINOXANE COCATALYSTS FOR BIS-PHENYLPHENOXY METAL-LIGAND COMPLEXES

Processes of polymerizing olefin monomers. The process comprising reacting ethylene and optionally one or more olefin monomers in the presence of a catalyst system, wherein the catalyst system comprises: hydrocarbyl-modified methylaluminoxane having less than 25 mole percent trihydrocarbyl aluminum...

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Hauptverfasser: MADENJIAN, Lisa S, VIGIL, Alfred E. Jr, JIN, Yi, HABERSBERGER, Brian M, PEARSON, David M, BOONE, Harold W
Format: Patent
Sprache:eng ; fre ; ger
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Zusammenfassung:Processes of polymerizing olefin monomers. The process comprising reacting ethylene and optionally one or more olefin monomers in the presence of a catalyst system, wherein the catalyst system comprises: hydrocarbyl-modified methylaluminoxane having less than 25 mole percent trihydrocarbyl aluminum compounds AlRA1RB1RC1 based on the total moles of aluminum, where RA1, RB1, and RC1 are independently linear (C1-C40)alkyl, branched (C1-C40)alkyl, or (C6-C40)aryl; and one or more metal-ligand complexes according to formula (I):