POWER STORAGE DEVICE PRE-DOPING AGENT AND PRODUCTION METHOD FOR SAME

The present invention relates to a pre-doping agent for a power storage device comprising a lithium iron oxide represented by Formula (1), wherein in X-ray diffractometry, a half width of a diffraction peak at a diffraction angle (2θ) of 23.6°±0.5° is 0.06° to 0.17°, and an intensity ratio (I44.6/I2...

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Bibliographische Detailangaben
Hauptverfasser: WATANABE, Keiichi, KAKIMOTO, Yuta, MITO, Shunsuke
Format: Patent
Sprache:eng ; fre ; ger
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Zusammenfassung:The present invention relates to a pre-doping agent for a power storage device comprising a lithium iron oxide represented by Formula (1), wherein in X-ray diffractometry, a half width of a diffraction peak at a diffraction angle (2θ) of 23.6°±0.5° is 0.06° to 0.17°, and an intensity ratio (I44.6/I23.6) of a diffraction peak intensity (I44.6) at a diffraction angle (2θ) of 44.6°±0.5° to a diffraction peak intensity (I23.6) at a diffraction angle (2θ) of 23.6°±0.5° is less than 8%. There is thus provided a pre-doping agent for a power storage device with a large irreversible capacity suitably used as a power storage device, which can suppress reduction in a volume energy density of a power storage device, can reduce a production cost, can prevent decomposition of an electrolytic solution because it allows for pre-doping with lithium ions at a lower charging voltage, has a high charging depth and a high discharge capacity, and can prevent occurrence of a short circuit.        LixFeOy     (1)wherein x meets 3.5≤x≤7.0 and y meets 3.1≤y≤5.0.