PROCESS FOR PREPARING CATALYSTS AND CATALYST COMPOSITIONS

Disclosed are support-activators and catalyst compositions comprising the support-activators for polymerizing olefins in which the support-activator includes clay heteroadduct, prepare from a colloidal phyllosilicate such as a colloidal smectite clay, which is chemically-modified with a heterocoagul...

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Bibliographische Detailangaben
Hauptverfasser: SHIH, Wei-Chun, CHUNG, Kevin, WANG, Daoyong, JOHNSON II, Charles R, JENSEN, Michael D, CHEN, Chih-Jian, XU, Guangxue, COWEN, Mary Lou
Format: Patent
Sprache:eng ; fre ; ger
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Zusammenfassung:Disclosed are support-activators and catalyst compositions comprising the support-activators for polymerizing olefins in which the support-activator includes clay heteroadduct, prepare from a colloidal phyllosilicate such as a colloidal smectite clay, which is chemically-modified with a heterocoagulation agent. By limiting the amount of heterocoagulation reagent relative to the colloidal smectite clay as described herein, the smectite heteroadduct support-activator is a porous and amorphous solid which can be readily isolated from the resulting slurry by a conventional filtration process, and which can activate metallocenes and related catalysts toward olefin polymerization. Related compositions and processes are disclosed.