B!S(ARYL PHENOLATE) LEWIS BASE CATALYSTS AND METHODS THEREOF

This invention relates to supported catalyst compositions of transition metal complexes of a dianionic, tridentate ligand that features a central neutral heterocyclic Lewis base and two phenolate donors, where the tridentate ligand coordinates to the metal center to form two eight- membered rings. P...

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Hauptverfasser: ZHOU, Hua, VOSKOBOYNIKOV, Alexander, Z, UBORSKY, Dmitry, V, CANICH, Jo Ann, M, HAGADORN, John, R, CAI, Irene, C, POPOV, Vladislav, A, GORYUNOV, Georgy, P
Format: Patent
Sprache:eng ; fre ; ger
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Zusammenfassung:This invention relates to supported catalyst compositions of transition metal complexes of a dianionic, tridentate ligand that features a central neutral heterocyclic Lewis base and two phenolate donors, where the tridentate ligand coordinates to the metal center to form two eight- membered rings. Preferably the bis(phenolate) complexes are represented by Formula (I): where M, L, X, m, n, E, E',Q, R1, R2, R3, R4, R1', R2', R3', R4', A1, A1', are as defined herein, where A1QA1' are part of a heterocyclic Lewis base containing 4 to 40 non-hydrogen atoms that links A2 to A2' via a 3-atom bridge with Q being the central atom of the 3 -atom bridge.