PROCESSES TO PRODUCE POLY ALPHA-OLEFIN TRIMER AND APPARATUS THEREFOR

In at least one embodiment, a process to produce a poly alpha-olefin (PAO) includes introducing a first alpha-olefin to a first catalyst system comprising activator and a metallocene compound into a continuous stirred tank reactor or a continuous tubular reactor under first reactor conditions to for...

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Hauptverfasser: CHEN, Patrick, C, RAPP, Jennifer, L, WAHN, Brian, H, KUZHIYIL, Najeeb, M, LI, Mark, H, YANG, Jian, NANDAPURKAR, Pramod, J, LOTFIZADEHDEHKORDI, Babak, EMETT, Craig, J
Format: Patent
Sprache:eng ; fre ; ger
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Zusammenfassung:In at least one embodiment, a process to produce a poly alpha-olefin (PAO) includes introducing a first alpha-olefin to a first catalyst system comprising activator and a metallocene compound into a continuous stirred tank reactor or a continuous tubular reactor under first reactor conditions to form a first reactor effluent. The first alpha-olefin is introduced to the reactor at a flow rate of about 100 g/hr or more. The first reactor effluent includes at least 60 wt% of PAO dimer and 40 wt% or less of higher oligomers, where the higher oligomers are oligomers that have a degree of polymerization of 3 or more. The process includes introducing the first reactor effluent and a second alpha-olefin to a second catalyst composition including an acid catalyst in a second reactor to form a second reactor effluent comprising PAO trimer.