MOLECULAR CATALYSTS FOR SELECTIVE HYDROGENOLYSIS OF AMIDES

A compound by the name 1,1,1-tris(di(3,5-dimethoxyphenyl)phosphino-methyl)ethane. The compound can be represented by the structure of formula (I):The compound is useful as a ligand for ruthenium to form an organometallic complex. The complex is an active catalyst for the hydrogenolysis of amides to...

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Bibliographische Detailangaben
Hauptverfasser: HEMBRE, Robert, Thomas, KLANKERMAYER, Jürgen, WESTHUES, Stefan, LEITNER, Walter
Format: Patent
Sprache:eng ; fre ; ger
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Zusammenfassung:A compound by the name 1,1,1-tris(di(3,5-dimethoxyphenyl)phosphino-methyl)ethane. The compound can be represented by the structure of formula (I):The compound is useful as a ligand for ruthenium to form an organometallic complex. The complex is an active catalyst for the hydrogenolysis of amides to form amines and optionally alcohols.