IRON-CATALYZED TRANSFER HYDROGENATION OF ESTERS TO ALCOHOLS

IRON-CATALYZED TRANSFER HYDROGENATION OF ESTERS TO ALCOHOLS

Iron-based homogeneous catalysts, supported by pincer ligands, are employed in the transfer hydrogenation of esters using C2-C12 alcohols as sacrificial hydrogen donors to produce corresponding alcohols from the esters. No external H2 pressure is required. The reaction can be carried out under ambie...

Ausführliche Beschreibung

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Bibliographische Detailangaben
Hauptverfasser: ADAMS, Steven, J, HEMBRE, Robert, Thomas, BARNICKI, Scott, Donald, SESHADRI, Vikram, CHAKRABORTY, Sumit
Format: Patent
Sprache:eng ; fre ; ger
Schlagworte:
ACYCLIC OR CARBOCYCLIC COMPOUNDS
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY
CHEMISTRY
METALLURGY
ORGANIC CHEMISTRY
PERFORMING OPERATIONS
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
THEIR RELEVANT APPARATUS
TRANSPORTING
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Zusammenfassung:Iron-based homogeneous catalysts, supported by pincer ligands, are employed in the transfer hydrogenation of esters using C2-C12 alcohols as sacrificial hydrogen donors to produce corresponding alcohols from the esters. No external H2 pressure is required. The reaction can be carried out under ambient pressure.