BLOCKING GROUPS FOR LIGHT POLYMERIZABLE RESINS USEFUL IN ADDITIVE MANUFACTURING

Provided herein is a method of forming a three-dimensional object in which the polymerizable liquid includes a mixture of (i) a light polymerizable first component, and (ii) a heat polymerizable second component; the heat polymerizable second component comprising (i) a first blocked reactive constit...

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Bibliographische Detailangaben
Hauptverfasser:	CHEN, Kai, WRIGHT, Andrew Gordon, ZHANG, Mu San
Format:	Patent
Sprache:	eng ; fre ; ger
Schlagworte:	AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING APPARATUS SPECIALLY ADAPTED THEREFOR CINEMATOGRAPHY ELECTROGRAPHY HOLOGRAPHY MATERIALS THEREFOR ORIGINALS THEREFOR PERFORMING OPERATIONS PHOTOGRAPHY PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES,e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTORDEVICES PHYSICS SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDEDFOR SHAPING OR JOINING OF PLASTICS TRANSPORTING WORKING OF PLASTICS WORKING OF SUBSTANCES IN A PLASTIC STATE, IN GENERAL
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Beschreibung
Zusammenfassung:	Provided herein is a method of forming a three-dimensional object in which the polymerizable liquid includes a mixture of (i) a light polymerizable first component, and (ii) a heat polymerizable second component; the heat polymerizable second component comprising (i) a first blocked reactive constituent that is blocked with a volatile blocking group, and optionally (ii) a curative. Upon heating a formed three-dimensional intermediate sufficiently, the volatile blocking group is cleaved and vaporizes out of the three-dimensional intermediate, to form the three-dimensional object. Also provided is a three-dimensional object produced by the method. Further provided is a polymerizable liquid composition useful for carrying out the method, and prepolymers and monomers useful for the polymerizable liquid composition.