PHOSPHORESCENT PtAg2 COMPLEX, PREPARATION METHOD THEREFOR AND USE THEREOF

The present invention relates to an ionic type phosphorescent metal complex with a racemization structure, a preparation method therefor and a use thereof. The structure of the complex is [PtAg{rac-(PPhCHPPhCH-)(C≡CR)(PR')]Aor [PtAg{meso-(PPhCHPPhCH-)}(C≡CR)(PR')(µ-X)]A, wherein R is the s...

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Hauptverfasser: CHEN, Zhongning, WANG, Jinyun, SHU, Huixing
Format: Patent
Sprache:eng ; fre ; ger
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Zusammenfassung:The present invention relates to an ionic type phosphorescent metal complex with a racemization structure, a preparation method therefor and a use thereof. The structure of the complex is [PtAg{rac-(PPhCHPPhCH-)(C≡CR)(PR')]Aor [PtAg{meso-(PPhCHPPhCH-)}(C≡CR)(PR')(µ-X)]A, wherein R is the same or different and is independently selected from alkyl, aryl, heteroaryl, and heteroaryl aryl; R' is the same or different and is independently selected from alkyl, aryl, and heteroaryl; the alkyl, aryl, and heteroaryl can be substituted by one or more substituents which are selected from alkyl, alkenyl, alkynyl, alkoxy, amino, halogen, halogenated alkyl, and aryl; X is halogen; Aand Aare monovalent or bivalent anions; and m or n is 1 or 2. The present invention also relates to an organic light emitting diode, a preparation method therefor and use thereof. The organic light emitting diode prepared by taking the phosphorescent metal complex of the present invention as a luminous layer dopant has high-performance organic electroluminescence and can be applied to panel display.