POLYMERIC MATERIALS
A polymeric material having a repeat unit of formula -O-Ph-O-Ph-CO-Ph- Iand a repeat unit of formula -O-Ph-Ph-O-Ph-CO-Ph- IIwherein Ph represents a phenylene moiety;wherein the repeat units I and II are in the relative molar properties I:II of from 65:35 to 95:5;wherein the p...
Gespeichert in:
Hauptverfasser: | , , , , , |
---|---|
Format: | Patent |
Sprache: | eng ; fre ; ger |
Schlagworte: | |
Online-Zugang: | Volltext bestellen |
Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
Zusammenfassung: | A polymeric material having a repeat unit of formula -O-Ph-O-Ph-CO-Ph- Iand a repeat unit of formula -O-Ph-Ph-O-Ph-CO-Ph- IIwherein Ph represents a phenylene moiety;wherein the repeat units I and II are in the relative molar properties I:II of from 65:35 to 95:5;wherein the polymer material has a crystallinity of at least 25% measured by differential scanning calorimetry as described in Example 31.A process for the production of a polymeric material having a repeat unit of formula -O-Ph-O-Ph-CO-Ph- Iand a repeat unit of formula -O-Ph-Ph-O-Ph-CO-Ph- IIwherein Ph represents a phenylene moiety, said process comprising polycondensing a mixture of at least one dihydroxybenzene compound and at least one dihydroxybiphenyl compound in the molar proportions 65:35 to 95:5 with at least one dihalobenzophenone in the presence of sodium carbonate and potassium carbonate wherein:(i) the mole% of said potassium carbonate is at least 2.5 and/or(ii) the following relationship (referred to as the "D50/mole% relationship") applies |
---|