SOLID ELECTROLYTE MATERIAL AND ALL SOLID LITHIUM ION SECONDARY BATTERY

There are provided a solid electrolyte material having high density and ion conductivity, and an all solid lithium ion secondary battery using the solid electrolyte material. The solid electrolyte material has a garnet-related structure which has a chemical composition represented by Li 7-x-y La 3 Z...

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Bibliographische Detailangaben
Hauptverfasser: TAKAMORI Chika, KATAOKA Kunimitsu, ISHIZAKI Haruo, AKIMOTO Junji
Format: Patent
Sprache:eng ; fre ; ger
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Beschreibung
Zusammenfassung:There are provided a solid electrolyte material having high density and ion conductivity, and an all solid lithium ion secondary battery using the solid electrolyte material. The solid electrolyte material has a garnet-related structure which has a chemical composition represented by Li 7-x-y La 3 Zr 2-x-y Ta x Nb y O 12 (0‰¤x‰¤0.8, 0.2‰¤y‰¤1, and 0.2‰¤x+y‰¤1) and relative density of 99% or greater, and belongs to a cubic system. The solid electrolyte material has lithium ion conductivity which is equal to or greater than 1.0 x 10 -3 S/cm. The solid electrolyte material has a lattice constant a which satisfies 1.28 nm‰¤a‰¤1.30 nm, and has a lithium ion which occupies only two or more 96h sites in a crystal structure. The all solid lithium ion secondary battery includes a positive electrode, a negative electrode, and a solid electrolyte. The solid electrolyte includes the solid electrolyte material.