COPOLYMERS OF PERFLUOROTRIVINYLTRIAZINE COMPOUNDS AND METHODS FOR SYNTHESIZING THE COPOLYMERS
Provided herein are copolymers that comprise copolymerized residues of a perfluorotrivinyltriazine monomer of Formula 1.Preferred Rf groups include, without limitation, -(CF2)n- (n=1-6); -(CF2)m-[OCF(CF3)CF2]p- (m=1-4, p=1-4); and -[(CF(CF3)-O)x-(CF2)k]- (x=1-3, k=1-5). Preferred comonomers for copo...
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Zusammenfassung: | Provided herein are copolymers that comprise copolymerized residues of a perfluorotrivinyltriazine monomer of Formula 1.Preferred Rf groups include, without limitation, -(CF2)n- (n=1-6); -(CF2)m-[OCF(CF3)CF2]p- (m=1-4, p=1-4); and -[(CF(CF3)-O)x-(CF2)k]- (x=1-3, k=1-5). Preferred comonomers for copolymerization with the perfluorotrivinyltriazine monomer (1) include, without limitation, tetrafluoroethylene (TFE); vinylidene fluoride (VF2); hexafluoropropylene (HFP); vinyl fluoride (VF); EVE; PSEPVE; perfluoro-(long chain vinyl ethers); E; P; PFBE; PEVE; EVE-OH; EVE-P; PDD; and the cure-site monomers BTFB, ITFB, 8-CNVE, 8-SAVE, and the like. Also provided are methods of synthesizing the copolymers and articles comprising the copolymers. |
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