CATALYST COMPOSITION FOR HYDROGENATION AND HYDROGENATION METHOD USING CATALYST COMPOSITION FOR HYDROGENATION
A catalyst composition for hydrogenation including (A) to (D), in which a mass ratio ((C)/(A)) is 0.1 to 4.0 and a mass ratio ((D)/(A)) is 0.01 to 1.00, (A): a titanocene compound represented by formula (1), (wherein R 5 and R 6 are any group selected from hydrogen, a hydrocarbon group having 1 to 1...
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Zusammenfassung: | A catalyst composition for hydrogenation including (A) to (D), in which a mass ratio ((C)/(A)) is 0.1 to 4.0 and a mass ratio ((D)/(A)) is 0.01 to 1.00,
(A): a titanocene compound represented by formula (1),
(wherein R 5 and R 6 are any group selected from hydrogen, a hydrocarbon group having 1 to 12 carbon atoms, an aryloxy group, an alkoxy group, a halogen group, and a carbonyl group. R 1 and R 2 are any group selected from the group consisting of hydrogen and a hydrocarbon group having 1 to 12 carbon atoms, and R 1 and R 2 are not all hydrogen atoms or all a hydrocarbon group having 1 to 12 carbon atoms),
(B): a reductant formed from a compound containing an element selected from the elements Li, Na, K, Mg, Zn, Al, and Ca,
(C): an unsaturated compound having a molecular weight of 400 or less, and
(D): a polar compound. |
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