Plug flow bulk polymerization of vinyl monomers

A process for continuous bulk polymerization is disclosed that includes providing a plug flow reactor comprising a primary loop reactor including a loop for recirculating a portion of a polymer-in-progress at a polymer flow rate back to a reactor in the primary loop reactor, introducing at least one...

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Bibliographische Detailangaben
Hauptverfasser:	Tynan Jr., John K, St Coeur, Richard W, Barbieri, Mark D, Lewandowski, Mark A
Format:	Patent
Sprache:	eng ; fre ; ger
Schlagworte:	AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING CHEMISTRY COMPOSITIONS BASED THEREON MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS METALLURGY ORGANIC MACROMOLECULAR COMPOUNDS PERFORMING OPERATIONS SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDEDFOR SHAPING OR JOINING OF PLASTICS THEIR PREPARATION OR CHEMICAL WORKING-UP TRANSPORTING WORKING OF PLASTICS WORKING OF SUBSTANCES IN A PLASTIC STATE, IN GENERAL
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Beschreibung
Zusammenfassung:	A process for continuous bulk polymerization is disclosed that includes providing a plug flow reactor comprising a primary loop reactor including a loop for recirculating a portion of a polymer-in-progress at a polymer flow rate back to a reactor in the primary loop reactor, introducing at least one monomer into the primary recirculation loop reactor at a monomer flow rate, polymerizing the monomer in the primary recirculation loop reactor in the presence of an initiator by way of a free-radical polymerization to form a polymer-in-progress, and recirculating a first portion of the polymer-in-progress through the loop into a reactor in the primary loop reactor to combine with the monomer at a ratio of polymer flow rate to monomer flow rate that is greater than 5.