Metal complex with a bridged cyclopentadienyl amidine ligand
The present invention relates to a new metal complex of the formula (1) wherein: M is a group 4-6 metal R 1 means is a substituent comprising a heteroatom of group 15, through which R 1 is bonded to the imine carbon atom; R 2 -R 5 are the same or different and each represents a hydrogen atom, an opt...
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Format: | Patent |
Sprache: | eng ; fre ; ger |
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Zusammenfassung: | The present invention relates to a new metal complex of the formula (1)
wherein:
M is a group 4-6 metal
R 1 means is a substituent comprising a heteroatom of group 15, through which R 1 is bonded to the imine carbon atom;
R 2 -R 5 are the same or different and each represents a hydrogen atom, an optionally substituted C1-10 alkyl group, an optionally substituted C1-10 alkoxy group, an optionally substituted C6-20 aryl group, an optionally substituted C6-20 aryloxy group, an optionally substituted C7-20 aralkyl group, an optionally substituted C7-20 aralkyloxy group, a silyl group substituted with optionally substituted C1-20 hydrocarbon group(s), a C1-20 hydrocarbon-substituted amino group or the adjacent R 2 -R 5 may be linked to each other to form a ring;
R 6 -R 9 are the same or different and each represents a hydrogen atom, a halogen atom, an optionally substituted C1-10 alkyl group, an optionally substituted C1-10 alkoxy group, an optionally substituted C6-20 aryl group, an optionally substituted C6-20 aryloxy group, an optionally substituted C7-20 aralkyl group, an optionally substituted C7-20 aralkyloxy group, a silyl
group substituted with optionally substituted C1-20 hydrocarbon group(s), a C1-20 hydrocarbon-substituted amino group or the adjacent R 6 -R 9 may be linked to each other to form a ring;
L is an optional neutral Lewis basic ligand, and j is an integer denoting the number of neutral ligands L; and
X is an anionic ligand, and r is an integer denoting the number of anionic ligands X. |
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