SULFUR-MODIFIED CHLOROPRENE RUBBER, MOLDING THEREOF, AND PRODUCTION METHOD THEREFOR

Provided are a sulfur-modified chloroprene rubber with reduced exothermicity, a molding thereof, and a production method therefor. A sulfur-modified chloroprene rubber modified at the polymer terminals with at least one compound selected from tetramethylthiuram disulfide, tetraalkylthiuram disulfide...

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Bibliographische Detailangaben
Hauptverfasser: OSE Motohiro, ABE Yasushi, SUZUKI Ryochi, KOBAYASHI Naoki
Format: Patent
Sprache:eng ; fre ; ger
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Zusammenfassung:Provided are a sulfur-modified chloroprene rubber with reduced exothermicity, a molding thereof, and a production method therefor. A sulfur-modified chloroprene rubber modified at the polymer terminals with at least one compound selected from tetramethylthiuram disulfide, tetraalkylthiuram disulfides with alkyl groups having a carbon number of 2 to 7 and dialkyldithiocarbamic acid salts with alkyl groups having a carbon number of 1 to 7, wherein there are peak tops at 3.55 to 3.61 ppm and at 3.41 to 3.47 ppm in 1 H-NMR spectrum, as determined in deuterochloroform solvent, wherein the ratio (A/B) of the peak area (A) at 3.55 to 3.61 ppm to the peak area (B) at 4.2 to 6.5 ppm is 0.05/100 to 0.50/100, and the extract with ethanol/toluene azeotropic mixture, as specified by JIS K 6229, is 3.0 to 9.0 mass %.