PLATINUM NICKEL CATALYST ALLOY

A Pt-Ni catalyst is provided which demonstrates an unusually high oxygen reduction mass activity. In some embodiments, the Pt-Ni catalyst is a Pt-Ni binary alloy. In some embodiments, the catalyst may be characterized as having a Pt fcc lattice parameter of less than 3.71 Angstroms or 0.371 nm. In s...

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Hauptverfasser: STEINBACH, Andrew J. L, DEBE, Mark K, VERNSTROM, George D
Format: Patent
Sprache:eng ; fre ; ger
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Zusammenfassung:A Pt-Ni catalyst is provided which demonstrates an unusually high oxygen reduction mass activity. In some embodiments, the Pt-Ni catalyst is a Pt-Ni binary alloy. In some embodiments, the catalyst may be characterized as having a Pt fcc lattice parameter of less than 3.71 Angstroms or 0.371 nm. In some embodiments the catalyst has a Pt fcc lattice parameter of between 3.69 Angstroms (or 0.369 nm) and 3.73 Angstroms (or 0.373 nm). In some embodiments, the catalyst may be characterized as having a composition of close to PtxNi(1-x), where x is between 0.2 and 0.4. In some embodiments the catalyst comprises nanostructured elements comprising microstructured support whiskers bearing a thin film of nanoscopic catalyst particles comprising a catalyst material described above. The catalyst may be particularly useful as a fuel cell catalyst and more specifically as a fuel cell cathode catalyst.