HIGH ACTIVITY ZIEGLER-NATTA CATALYSTS, PROCESS FOR PRODUCING CATALYST AND USE THEREOF

HIGH ACTIVITY ZIEGLER-NATTA CATALYSTS, PROCESS FOR PRODUCING CATALYST AND USE THEREOF

Improved Ziegler-Natta catalysts and methods of making the improved catalyst are described. The Ziegler-Natta catalyst is formed using a spherical MgCl2-xROH support, where R is a linear, cyclic or branched hydrocarbon unit with 1-10 carbon atoms and where ROH is an alcohol or a mixture of at least...

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Bibliographische Detailangaben
Hauptverfasser: LANGHAUSER, FRANZ, KLENDWORTH, DOUGLAS, D, JOHNSON, KENNETH, W, WINTER, ANDREAS
Format: Patent
Sprache:eng ; fre ; ger
Schlagworte:
CHEMISTRY
COMPOSITIONS BASED THEREON
MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS
METALLURGY
ORGANIC MACROMOLECULAR COMPOUNDS
THEIR PREPARATION OR CHEMICAL WORKING-UP
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Beschreibung
Zusammenfassung:Improved Ziegler-Natta catalysts and methods of making the improved catalyst are described. The Ziegler-Natta catalyst is formed using a spherical MgCl2-xROH support, where R is a linear, cyclic or branched hydrocarbon unit with 1-10 carbon atoms and where ROH is an alcohol or a mixture of at least two different alcohols and where x has a range of about 1.5 to 6.0, preferably about 2.5 to 4, more preferably about 2.9 to 3.4, and even more preferably 2.95 to 3.35. The Ziegler-Natta catalyst includes a Group 4-8 transition metal and an internal donor. The catalyst has improved activity in olefin polymerization reactions as well as good stereoregularity and hydrogen sensitivity.