PROCESS OF OXIDATIVE DEHYDROGENATION USING A BORIA-ALUMINA CATALYST

The invention relates to a process of oxydehydrogenating an alkyl-substituted aromatic hydrocarbon starting compound into the corresponding alkenyl-substituted aromatic hydrocarbon product, respectively, which process comprises a step of contacting the starting compound and an oxidant at dehydrogena...

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Bibliographische Detailangaben
Hauptverfasser: AL-HAMED, YAHIA, AL-ZAHRANI, ABDULRAHIM, EL-YAHYAOUI, KHALID, K, DAOUS, MOHAMMAD
Format: Patent
Sprache:eng ; fre ; ger
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Beschreibung
Zusammenfassung:The invention relates to a process of oxydehydrogenating an alkyl-substituted aromatic hydrocarbon starting compound into the corresponding alkenyl-substituted aromatic hydrocarbon product, respectively, which process comprises a step of contacting the starting compound and an oxidant at dehydrogenating conditions, in the presence of a boria-alumina catalyst, characterized in that the boria-alumina catalyst has been prepared by a co-precipitation method. The co-precipitation method comprises the steps of preparing a solution of aluminium salt in an organic medium, followed by adding to this solution a boron compound and then adding ammonia gas to the mixture obtained in previous step to form a precipitate and/or a gel. This process enables oxydehydrogenation of ethyl-benzene to styrene with high selectivity.