Silanes and polysiloxanes
Monomeric silane compound (XXXV) obtained by reacting a silane compound (II) with a polyether amine compound (III), or a compound (T), which is e.g. 3-morpholin-4-yl-propylamine or 3-(2-aminoethyl)-aminopropyl-methyl-silsesquioxane with terminal methoxy group, is new. Monomeric silane compound of fo...
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| creator | SUESS, SABRINA TSCHIDA, GUENTHER LINDMAIR, GABRIELE CHROBACZEK, HARALD |
| description | Monomeric silane compound (XXXV) obtained by reacting a silane compound (II) with a polyether amine compound (III), or a compound (T), which is e.g. 3-morpholin-4-yl-propylamine or 3-(2-aminoethyl)-aminopropyl-methyl-silsesquioxane with terminal methoxy group, is new. Monomeric silane compound of formula ((RO) 2-Si(R 20>)(R 1>)) (XXXV) obtained by reacting a silane compound of formula (II) with a polyether amine compound (III) of formula (CH 3-(O-CH 2-CH 2) k-(O-CH 2-CH(CH 3) l-NH 2)), or (NH 2-(CH(CH 3)-CH 2-O) l-CH 2-CH(CH 3)-NH 2) or H 2N-CH(CH 3)-CH 2-(O-CH 2-CH(CH 3) l-(O-CH 2-CH 2) k-(O-CH 2-CH(CH 3)) l-NH 2, or NH 2-CH(CH 3)-CH 2-(O-CH(CH 3)-CH 2) w-O-CH 2-C-(CH 2-O-(CH 2-CH(CH 3)-O) w-CH 2-CH(CH 3)-NH 2) 3, or a compound (T), which is 3-morpholin-4-yl-propylamine, H 2N-CH 2-CH 2-CH 2-Si(CH 3)-(O-Si(CH 3) 3) 2, HO-(CH 2-CH 2-O) k-((CH(R 3>)) 2-O) l-CH 2-CH 2-CH 2-Si(CH 3)-(O-Si(CH 3) 3)) 2or 3-(2-aminoethyl)-aminopropyl-methyl-silsesquioxane with terminal methoxy group, is new. R : phenyl residue or 1-18C-alkyl, preferably CH 3or CH 2-CH 3; R 1>R, OR or methyl-phenyl-amine moiety; R 20>-R 21>-NH-(CH 2) 2-C(=O)-O-R 22>-O-C(=O)-(CH 2) 2-NH-R 21>-Si(OR) 2(R 1>) (XXXVI), -R 21>-NH-(CH 2) 2-C(=O)-O-R 23>(XXXVII), -R 21>-NH-(CH 2) 2-C(=O)-O-(CH 2-CH 2-O) k-(CH(R 3>)-CH(R 3>)-O) l-R23a) (XXXVIII), -R 22>-NH-(CH 2) 2-C(=O)-N(R 24>) 2(XXXIX), -R21a-CH(OH)-CH 2-NH-R21a-NH-CH 2-CH(OH)-R21a-Si(OR) 2(R 1>) (XL), silane substituted cyclohexane group of formula (XL1), -R 21>-NH-C(=O)-O-CH 2-CH(R)-OH (XL1a), -R 21>-NH-C(=O)-O-CH(R)-CH 2-OH (XL1b), -R 21>-NH-CH 2-CH(R)-OH (XL1c), -R 21>-NH-CH(R)-CH 2-OH (XL1d), -R 21>-NH-C(=O)-O-CH 2-CH(R)-O-C(=O)-CH=CH 2(XL1e), -R 21>-NH-C(=O)-O-CH(R) -CH 2-O-C(=O)-CH=CH 2(XL1f), -R 21>-NH-CH 2-CH(R)-O-C(=O)-CH=CH 2(XL1g) or -R 21>-NH-CH(R)-CH 2-C(=O)-CH=CH 2(XL1h); R 21>3-8C-alkylene (which is interrupted by one or more NH-bonds), or formula (i); R21a : R 21>or a bivalent residue of formula -CH 2-CH 2-NH-CH 2-CH(CH 3)-CH 2-Si(CH 3) 2-O-Si(CH 3) 2-CH 2-CH(CH 3)-CH 2-NH-CH 2-CH 2-; R 22>6-18C-alkylene, -CH 2-CH 2-O-C(=O)-NH-R 21>-NH-C(=O)-O-R 21>-O-C(=O)-NH-R 21>-NH-C(=O)-O-CH 2-CH 2-, or -CH 2-CH 2-O-C(=O)-(CH 2) 5-O-C(=O)-NH-R 21>-NH-C(=O)-O-CH 2-CH 2-; R 23>8-16C-alkyl, -(CH 2-CH 2-O-), or -(CH(R 3>)-CH(R 3>)-O-); R23a : 8-16C-alkyl or H; R 3>H or CH 3; either k, l : 1-22; or k+l : 3-25; R 24>1-6C-alkyl; x : 0-1500, preferably 10-1500; and w : 2-8. An independent claim is included for a polyorganosiloxane compound obtained by rea |
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| fullrecord | <record><control><sourceid>epo_EVB</sourceid><recordid>TN_cdi_epo_espacenet_EP2103622A1</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>EP2103622A1</sourcerecordid><originalsourceid>FETCH-epo_espacenet_EP2103622A13</originalsourceid><addsrcrecordid>eNrjZJAMzsxJzEstVkjMS1EoyM-pLM7Mya8AifAwsKYl5hSn8kJpbgYFN9cQZw_d1IL8-NTigsTk1LzUknjXACNDA2MzIyNHQ2MilAAA7uoiZA</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>patent</recordtype></control><display><type>patent</type><title>Silanes and polysiloxanes</title><source>esp@cenet</source><creator>SUESS, SABRINA ; TSCHIDA, GUENTHER ; LINDMAIR, GABRIELE ; CHROBACZEK, HARALD</creator><creatorcontrib>SUESS, SABRINA ; TSCHIDA, GUENTHER ; LINDMAIR, GABRIELE ; CHROBACZEK, HARALD</creatorcontrib><description>Monomeric silane compound (XXXV) obtained by reacting a silane compound (II) with a polyether amine compound (III), or a compound (T), which is e.g. 3-morpholin-4-yl-propylamine or 3-(2-aminoethyl)-aminopropyl-methyl-silsesquioxane with terminal methoxy group, is new. Monomeric silane compound of formula ((RO) 2-Si(R 20>)(R 1>)) (XXXV) obtained by reacting a silane compound of formula (II) with a polyether amine compound (III) of formula (CH 3-(O-CH 2-CH 2) k-(O-CH 2-CH(CH 3) l-NH 2)), or (NH 2-(CH(CH 3)-CH 2-O) l-CH 2-CH(CH 3)-NH 2) or H 2N-CH(CH 3)-CH 2-(O-CH 2-CH(CH 3) l-(O-CH 2-CH 2) k-(O-CH 2-CH(CH 3)) l-NH 2, or NH 2-CH(CH 3)-CH 2-(O-CH(CH 3)-CH 2) w-O-CH 2-C-(CH 2-O-(CH 2-CH(CH 3)-O) w-CH 2-CH(CH 3)-NH 2) 3, or a compound (T), which is 3-morpholin-4-yl-propylamine, H 2N-CH 2-CH 2-CH 2-Si(CH 3)-(O-Si(CH 3) 3) 2, HO-(CH 2-CH 2-O) k-((CH(R 3>)) 2-O) l-CH 2-CH 2-CH 2-Si(CH 3)-(O-Si(CH 3) 3)) 2or 3-(2-aminoethyl)-aminopropyl-methyl-silsesquioxane with terminal methoxy group, is new. R : phenyl residue or 1-18C-alkyl, preferably CH 3or CH 2-CH 3; R 1>R, OR or methyl-phenyl-amine moiety; R 20>-R 21>-NH-(CH 2) 2-C(=O)-O-R 22>-O-C(=O)-(CH 2) 2-NH-R 21>-Si(OR) 2(R 1>) (XXXVI), -R 21>-NH-(CH 2) 2-C(=O)-O-R 23>(XXXVII), -R 21>-NH-(CH 2) 2-C(=O)-O-(CH 2-CH 2-O) k-(CH(R 3>)-CH(R 3>)-O) l-R23a) (XXXVIII), -R 22>-NH-(CH 2) 2-C(=O)-N(R 24>) 2(XXXIX), -R21a-CH(OH)-CH 2-NH-R21a-NH-CH 2-CH(OH)-R21a-Si(OR) 2(R 1>) (XL), silane substituted cyclohexane group of formula (XL1), -R 21>-NH-C(=O)-O-CH 2-CH(R)-OH (XL1a), -R 21>-NH-C(=O)-O-CH(R)-CH 2-OH (XL1b), -R 21>-NH-CH 2-CH(R)-OH (XL1c), -R 21>-NH-CH(R)-CH 2-OH (XL1d), -R 21>-NH-C(=O)-O-CH 2-CH(R)-O-C(=O)-CH=CH 2(XL1e), -R 21>-NH-C(=O)-O-CH(R) -CH 2-O-C(=O)-CH=CH 2(XL1f), -R 21>-NH-CH 2-CH(R)-O-C(=O)-CH=CH 2(XL1g) or -R 21>-NH-CH(R)-CH 2-C(=O)-CH=CH 2(XL1h); R 21>3-8C-alkylene (which is interrupted by one or more NH-bonds), or formula (i); R21a : R 21>or a bivalent residue of formula -CH 2-CH 2-NH-CH 2-CH(CH 3)-CH 2-Si(CH 3) 2-O-Si(CH 3) 2-CH 2-CH(CH 3)-CH 2-NH-CH 2-CH 2-; R 22>6-18C-alkylene, -CH 2-CH 2-O-C(=O)-NH-R 21>-NH-C(=O)-O-R 21>-O-C(=O)-NH-R 21>-NH-C(=O)-O-CH 2-CH 2-, or -CH 2-CH 2-O-C(=O)-(CH 2) 5-O-C(=O)-NH-R 21>-NH-C(=O)-O-CH 2-CH 2-; R 23>8-16C-alkyl, -(CH 2-CH 2-O-), or -(CH(R 3>)-CH(R 3>)-O-); R23a : 8-16C-alkyl or H; R 3>H or CH 3; either k, l : 1-22; or k+l : 3-25; R 24>1-6C-alkyl; x : 0-1500, preferably 10-1500; and w : 2-8. An independent claim is included for a polyorganosiloxane compound obtained by reacting polyorganosiloxane compound of formula ((R 7>)(R) 2-Si-O-(Si(R)(R 6>)-O) x-Si(R) 2(R 7>)) (VIII) or its mixture with (XXXV) or a silane compound of formula (Si(OR) 2(R 1>)(R 2>)) (I). R 6>R or -(O-Si(R) 2) y-O-Si(R) 2-R 7>(IX); y : 0-500; R 7>R, OH or OR; R 2>vinyl residue, 1-18C-alkyl (which is optionally substituted by one or more quaternary amino-, amido-, mercapto-, epoxy-, phosphono- group, OH or F), -R 4>-O-CH 2-CH(O-R 5>)-CH 2-O-R 5>, -R 4>-NH-C(=O)-(CH 2) 3-O-C(=O)-C(R 3>)=CH 2, -R 4>-NH-((CH 2) 2-NH) p-C(=O)-(CH 2) 3-O-C(=O)-C(R 3>)=CH 2, -R 4>-O-C(=O)-C(R 3>)=CH 2, -(CH 2) 3-O-CH 2-C(R)-(CH 2-O-C(=O)-C(R 3>)=CH 2) 2, -R 4>-NH-CH(R 9>)-CH(R 3>)-COOR 8>, -R 4>-NH-CH 2-CH 2-NH-CH(R 9>)-CH(R 3>)-COOR 8>, -R 4>-R 10>-R 4>-Si(OR) 2(R 1>), -R 4>-(NH-CH 2-CH 2) p-NH-(CH(R 3>)) 2-C(=O)-N(R) 2, -R 4>-(NH-CH 2-CH 2) p-NH-(CH(R 3>)) 2-C(=O)-O-R 14>, -R 4>-(NH-CH 2-CH 2) p-NH-C(=O)-CH 2-CH 2-CH 2-OH, methyl-phenyl-amine moiety, -R 4>-(N(R 16>)-CH 2-CH 2) p-N(R 16>)-(C(=O)-O) f-CH(R)-CH 2-OH, -R 4>-(N(R 16>)-CH 2-CH 2) p-N(R 16>)-(C(=O)-O) f-CH(R)-CH 2-O-C(=O)-CH=CH 2, -R 4>-O-CH 2-CH(OH)-CH 2-NH-(CH 2-CH 2-O) u-A-((CH(R 3>)) 2-O-) v-R 17>, -R 4>-O-CH 2-CH(OH)-CH 2-N(R 13>)-(CH 2) 3-M, hydroxyl group substituted cyclohexane group of formula (XVIIIa), -R 4>-O-CH 2-CH(OH)-CH 2-O-(CH 2-CH 2-O) k-((CH(R 3>)) 2-O) l-(CH 2) 3-Si((O-Si(CH 3) 3) 2(CH 3), -R 4>-(NH-CH 2-CH 2) p-NH-CH 2-CH(OH)-CH 2-RF, -R 4>-(NH-CH 2-CH 2) p-NH-CH(CH 2OH)-RF, -R 4>-(NH-CH 2-CH 2) p-NH-CH 2-CH(OH)-CH 2-O-C(=O)-C(R 3>)=CH 2or -R 4>-(NH-CH 2-CH 2) p-NH-CH 2-CH(OH)-CH 2-NR 2>; A : a direct bond or a divalent residue of formula -CH 2-C(R 12>)(CH 2-O-(CH(R 3>)) 2-O) s-R 17>)-CH 2-O-; R 5>(-C(=O)-C(R 3>)=CH 2) or H; p : 0-2; R 4>a bivalent 1-4C-hydrocarbon; R 8>H, CH 3, C 2H 5or CH 2CH 2-OH; R 9>H or COOR 8>; R 14>H, 1-18C-alkyl or -R 4>-O-CH 2-CH(OH)-CH 2-O-(CH 2-CH 2-O) k-((CH(R 3>)) 2-O) l-(CH 2) 3-Si(OSi(CH 3) 3) 2(CH 3) (where the single units -(CH 2-CH 2-O)- and -(CHR 3>-CHR 3>-O)-); f : 0 or 1; R 16>H, -(C(=O)-O) f-CH(R)-CH 2-OH or -(C(=O)-O) f-CH(R)-CH 2-O-C(=O)-CH=CH 2; u, v, s : a value, which makes the equivalent weight of the residue R 2>of 100-5000, where one or two of u, v and s is 0; R 12>H or C 2H 5; R 17>R, -R 4>-NH 2or -CH 2-CH(CH 3)-NH-CH 2-CH(OH)-CH 2-O-R 4>-Si(OR) 2(R 1>); M : OR, N(R) 2, morpholine or -Si(CH 3)-(OSi(CH 3) 3) 2; RF : 5-23C-perfluoroalkyl; R 10>a divalent residue of formula -O-CH 2-CH(OH)-CH 2-N(R 13>)-R 11>-N(R 13>)-CH 2-CH(OH)-CH 2-O-, hydroxyl group substituted cyclohexane group of formula (XXII), -(NH-CH 2-CH 2) p-NH-(CH(R 3>)) 2-C(=O)-O-K 1>-O-C(=O)-(CH(R 3>)) 2-NH-(CH 2-CH 2-NH) p-, amide substituted cyclohexane group of formula (XXIV), or substituted benzene group of formula (XXIVa), -(CH 2) 2-NH-(CH 2) 2-, piperazine group of formula (XXVI), bis-methyl-benzen-1,4-yl, 1-chloro-4-[(4-chlorophenyl)methyl]benzene, methyl-1,3,3-trimethyl-cyclohexan-1,5-yl, -(CH 2) 2-NH-R 4>-(Si(R) 2-O) z-Si(R) 2-R 4>-NH-(CH 2) 2or -R 4>-(Si(R) 2-O) z-Si(R) 2-R 4>-, where complete or a part of N in the above formula are not a part of an amide group and exists in quaternized form; z : 8-500, preferably 8-20; f : 0 or 1; K 1>2-18C-alkylene; R 11>-(CH 2) d-; d : 1-6; and R 13>H, CH(CH 3) 2or CH 2-CH(CH 3) 3. [Image] [Image] [Image] [Image] [Image] [Image].
Silane der Formel
und neue Polysiloxane werden beschrieben, wobei die Polysiloxane durch Umsetzung von Polyorganosiloxanen mit Silanen der oben angegebenen Formel oder mit Silanen der Formel
hergestellt werden können. Die so erhaltenen neuen Polysiloxane eignen sich unter anderem für die Behandlung von textilen Flächengebilden aus natürlichen oder synthetischen Fasern.</description><language>eng ; fre ; ger</language><subject>ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM ; CHEMISTRY ; METALLURGY ; ORGANIC CHEMISTRY</subject><creationdate>2009</creationdate><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=20090923&DB=EPODOC&CC=EP&NR=2103622A1$$EHTML$$P50$$Gepo$$Hfree_for_read</linktohtml><link.rule.ids>230,308,780,885,25564,76547</link.rule.ids><linktorsrc>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=20090923&DB=EPODOC&CC=EP&NR=2103622A1$$EView_record_in_European_Patent_Office$$FView_record_in_$$GEuropean_Patent_Office$$Hfree_for_read</linktorsrc></links><search><creatorcontrib>SUESS, SABRINA</creatorcontrib><creatorcontrib>TSCHIDA, GUENTHER</creatorcontrib><creatorcontrib>LINDMAIR, GABRIELE</creatorcontrib><creatorcontrib>CHROBACZEK, HARALD</creatorcontrib><title>Silanes and polysiloxanes</title><description>Monomeric silane compound (XXXV) obtained by reacting a silane compound (II) with a polyether amine compound (III), or a compound (T), which is e.g. 3-morpholin-4-yl-propylamine or 3-(2-aminoethyl)-aminopropyl-methyl-silsesquioxane with terminal methoxy group, is new. Monomeric silane compound of formula ((RO) 2-Si(R 20>)(R 1>)) (XXXV) obtained by reacting a silane compound of formula (II) with a polyether amine compound (III) of formula (CH 3-(O-CH 2-CH 2) k-(O-CH 2-CH(CH 3) l-NH 2)), or (NH 2-(CH(CH 3)-CH 2-O) l-CH 2-CH(CH 3)-NH 2) or H 2N-CH(CH 3)-CH 2-(O-CH 2-CH(CH 3) l-(O-CH 2-CH 2) k-(O-CH 2-CH(CH 3)) l-NH 2, or NH 2-CH(CH 3)-CH 2-(O-CH(CH 3)-CH 2) w-O-CH 2-C-(CH 2-O-(CH 2-CH(CH 3)-O) w-CH 2-CH(CH 3)-NH 2) 3, or a compound (T), which is 3-morpholin-4-yl-propylamine, H 2N-CH 2-CH 2-CH 2-Si(CH 3)-(O-Si(CH 3) 3) 2, HO-(CH 2-CH 2-O) k-((CH(R 3>)) 2-O) l-CH 2-CH 2-CH 2-Si(CH 3)-(O-Si(CH 3) 3)) 2or 3-(2-aminoethyl)-aminopropyl-methyl-silsesquioxane with terminal methoxy group, is new. R : phenyl residue or 1-18C-alkyl, preferably CH 3or CH 2-CH 3; R 1>R, OR or methyl-phenyl-amine moiety; R 20>-R 21>-NH-(CH 2) 2-C(=O)-O-R 22>-O-C(=O)-(CH 2) 2-NH-R 21>-Si(OR) 2(R 1>) (XXXVI), -R 21>-NH-(CH 2) 2-C(=O)-O-R 23>(XXXVII), -R 21>-NH-(CH 2) 2-C(=O)-O-(CH 2-CH 2-O) k-(CH(R 3>)-CH(R 3>)-O) l-R23a) (XXXVIII), -R 22>-NH-(CH 2) 2-C(=O)-N(R 24>) 2(XXXIX), -R21a-CH(OH)-CH 2-NH-R21a-NH-CH 2-CH(OH)-R21a-Si(OR) 2(R 1>) (XL), silane substituted cyclohexane group of formula (XL1), -R 21>-NH-C(=O)-O-CH 2-CH(R)-OH (XL1a), -R 21>-NH-C(=O)-O-CH(R)-CH 2-OH (XL1b), -R 21>-NH-CH 2-CH(R)-OH (XL1c), -R 21>-NH-CH(R)-CH 2-OH (XL1d), -R 21>-NH-C(=O)-O-CH 2-CH(R)-O-C(=O)-CH=CH 2(XL1e), -R 21>-NH-C(=O)-O-CH(R) -CH 2-O-C(=O)-CH=CH 2(XL1f), -R 21>-NH-CH 2-CH(R)-O-C(=O)-CH=CH 2(XL1g) or -R 21>-NH-CH(R)-CH 2-C(=O)-CH=CH 2(XL1h); R 21>3-8C-alkylene (which is interrupted by one or more NH-bonds), or formula (i); R21a : R 21>or a bivalent residue of formula -CH 2-CH 2-NH-CH 2-CH(CH 3)-CH 2-Si(CH 3) 2-O-Si(CH 3) 2-CH 2-CH(CH 3)-CH 2-NH-CH 2-CH 2-; R 22>6-18C-alkylene, -CH 2-CH 2-O-C(=O)-NH-R 21>-NH-C(=O)-O-R 21>-O-C(=O)-NH-R 21>-NH-C(=O)-O-CH 2-CH 2-, or -CH 2-CH 2-O-C(=O)-(CH 2) 5-O-C(=O)-NH-R 21>-NH-C(=O)-O-CH 2-CH 2-; R 23>8-16C-alkyl, -(CH 2-CH 2-O-), or -(CH(R 3>)-CH(R 3>)-O-); R23a : 8-16C-alkyl or H; R 3>H or CH 3; either k, l : 1-22; or k+l : 3-25; R 24>1-6C-alkyl; x : 0-1500, preferably 10-1500; and w : 2-8. An independent claim is included for a polyorganosiloxane compound obtained by reacting polyorganosiloxane compound of formula ((R 7>)(R) 2-Si-O-(Si(R)(R 6>)-O) x-Si(R) 2(R 7>)) (VIII) or its mixture with (XXXV) or a silane compound of formula (Si(OR) 2(R 1>)(R 2>)) (I). R 6>R or -(O-Si(R) 2) y-O-Si(R) 2-R 7>(IX); y : 0-500; R 7>R, OH or OR; R 2>vinyl residue, 1-18C-alkyl (which is optionally substituted by one or more quaternary amino-, amido-, mercapto-, epoxy-, phosphono- group, OH or F), -R 4>-O-CH 2-CH(O-R 5>)-CH 2-O-R 5>, -R 4>-NH-C(=O)-(CH 2) 3-O-C(=O)-C(R 3>)=CH 2, -R 4>-NH-((CH 2) 2-NH) p-C(=O)-(CH 2) 3-O-C(=O)-C(R 3>)=CH 2, -R 4>-O-C(=O)-C(R 3>)=CH 2, -(CH 2) 3-O-CH 2-C(R)-(CH 2-O-C(=O)-C(R 3>)=CH 2) 2, -R 4>-NH-CH(R 9>)-CH(R 3>)-COOR 8>, -R 4>-NH-CH 2-CH 2-NH-CH(R 9>)-CH(R 3>)-COOR 8>, -R 4>-R 10>-R 4>-Si(OR) 2(R 1>), -R 4>-(NH-CH 2-CH 2) p-NH-(CH(R 3>)) 2-C(=O)-N(R) 2, -R 4>-(NH-CH 2-CH 2) p-NH-(CH(R 3>)) 2-C(=O)-O-R 14>, -R 4>-(NH-CH 2-CH 2) p-NH-C(=O)-CH 2-CH 2-CH 2-OH, methyl-phenyl-amine moiety, -R 4>-(N(R 16>)-CH 2-CH 2) p-N(R 16>)-(C(=O)-O) f-CH(R)-CH 2-OH, -R 4>-(N(R 16>)-CH 2-CH 2) p-N(R 16>)-(C(=O)-O) f-CH(R)-CH 2-O-C(=O)-CH=CH 2, -R 4>-O-CH 2-CH(OH)-CH 2-NH-(CH 2-CH 2-O) u-A-((CH(R 3>)) 2-O-) v-R 17>, -R 4>-O-CH 2-CH(OH)-CH 2-N(R 13>)-(CH 2) 3-M, hydroxyl group substituted cyclohexane group of formula (XVIIIa), -R 4>-O-CH 2-CH(OH)-CH 2-O-(CH 2-CH 2-O) k-((CH(R 3>)) 2-O) l-(CH 2) 3-Si((O-Si(CH 3) 3) 2(CH 3), -R 4>-(NH-CH 2-CH 2) p-NH-CH 2-CH(OH)-CH 2-RF, -R 4>-(NH-CH 2-CH 2) p-NH-CH(CH 2OH)-RF, -R 4>-(NH-CH 2-CH 2) p-NH-CH 2-CH(OH)-CH 2-O-C(=O)-C(R 3>)=CH 2or -R 4>-(NH-CH 2-CH 2) p-NH-CH 2-CH(OH)-CH 2-NR 2>; A : a direct bond or a divalent residue of formula -CH 2-C(R 12>)(CH 2-O-(CH(R 3>)) 2-O) s-R 17>)-CH 2-O-; R 5>(-C(=O)-C(R 3>)=CH 2) or H; p : 0-2; R 4>a bivalent 1-4C-hydrocarbon; R 8>H, CH 3, C 2H 5or CH 2CH 2-OH; R 9>H or COOR 8>; R 14>H, 1-18C-alkyl or -R 4>-O-CH 2-CH(OH)-CH 2-O-(CH 2-CH 2-O) k-((CH(R 3>)) 2-O) l-(CH 2) 3-Si(OSi(CH 3) 3) 2(CH 3) (where the single units -(CH 2-CH 2-O)- and -(CHR 3>-CHR 3>-O)-); f : 0 or 1; R 16>H, -(C(=O)-O) f-CH(R)-CH 2-OH or -(C(=O)-O) f-CH(R)-CH 2-O-C(=O)-CH=CH 2; u, v, s : a value, which makes the equivalent weight of the residue R 2>of 100-5000, where one or two of u, v and s is 0; R 12>H or C 2H 5; R 17>R, -R 4>-NH 2or -CH 2-CH(CH 3)-NH-CH 2-CH(OH)-CH 2-O-R 4>-Si(OR) 2(R 1>); M : OR, N(R) 2, morpholine or -Si(CH 3)-(OSi(CH 3) 3) 2; RF : 5-23C-perfluoroalkyl; R 10>a divalent residue of formula -O-CH 2-CH(OH)-CH 2-N(R 13>)-R 11>-N(R 13>)-CH 2-CH(OH)-CH 2-O-, hydroxyl group substituted cyclohexane group of formula (XXII), -(NH-CH 2-CH 2) p-NH-(CH(R 3>)) 2-C(=O)-O-K 1>-O-C(=O)-(CH(R 3>)) 2-NH-(CH 2-CH 2-NH) p-, amide substituted cyclohexane group of formula (XXIV), or substituted benzene group of formula (XXIVa), -(CH 2) 2-NH-(CH 2) 2-, piperazine group of formula (XXVI), bis-methyl-benzen-1,4-yl, 1-chloro-4-[(4-chlorophenyl)methyl]benzene, methyl-1,3,3-trimethyl-cyclohexan-1,5-yl, -(CH 2) 2-NH-R 4>-(Si(R) 2-O) z-Si(R) 2-R 4>-NH-(CH 2) 2or -R 4>-(Si(R) 2-O) z-Si(R) 2-R 4>-, where complete or a part of N in the above formula are not a part of an amide group and exists in quaternized form; z : 8-500, preferably 8-20; f : 0 or 1; K 1>2-18C-alkylene; R 11>-(CH 2) d-; d : 1-6; and R 13>H, CH(CH 3) 2or CH 2-CH(CH 3) 3. [Image] [Image] [Image] [Image] [Image] [Image].
Silane der Formel
und neue Polysiloxane werden beschrieben, wobei die Polysiloxane durch Umsetzung von Polyorganosiloxanen mit Silanen der oben angegebenen Formel oder mit Silanen der Formel
hergestellt werden können. Die so erhaltenen neuen Polysiloxane eignen sich unter anderem für die Behandlung von textilen Flächengebilden aus natürlichen oder synthetischen Fasern.</description><subject>ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM</subject><subject>CHEMISTRY</subject><subject>METALLURGY</subject><subject>ORGANIC CHEMISTRY</subject><fulltext>true</fulltext><rsrctype>patent</rsrctype><creationdate>2009</creationdate><recordtype>patent</recordtype><sourceid>EVB</sourceid><recordid>eNrjZJAMzsxJzEstVkjMS1EoyM-pLM7Mya8AifAwsKYl5hSn8kJpbgYFN9cQZw_d1IL8-NTigsTk1LzUknjXACNDA2MzIyNHQ2MilAAA7uoiZA</recordid><startdate>20090923</startdate><enddate>20090923</enddate><creator>SUESS, SABRINA</creator><creator>TSCHIDA, GUENTHER</creator><creator>LINDMAIR, GABRIELE</creator><creator>CHROBACZEK, HARALD</creator><scope>EVB</scope></search><sort><creationdate>20090923</creationdate><title>Silanes and polysiloxanes</title><author>SUESS, SABRINA ; TSCHIDA, GUENTHER ; LINDMAIR, GABRIELE ; CHROBACZEK, HARALD</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-epo_espacenet_EP2103622A13</frbrgroupid><rsrctype>patents</rsrctype><prefilter>patents</prefilter><language>eng ; fre ; ger</language><creationdate>2009</creationdate><topic>ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM</topic><topic>CHEMISTRY</topic><topic>METALLURGY</topic><topic>ORGANIC CHEMISTRY</topic><toplevel>online_resources</toplevel><creatorcontrib>SUESS, SABRINA</creatorcontrib><creatorcontrib>TSCHIDA, GUENTHER</creatorcontrib><creatorcontrib>LINDMAIR, GABRIELE</creatorcontrib><creatorcontrib>CHROBACZEK, HARALD</creatorcontrib><collection>esp@cenet</collection></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext_linktorsrc</fulltext></delivery><addata><au>SUESS, SABRINA</au><au>TSCHIDA, GUENTHER</au><au>LINDMAIR, GABRIELE</au><au>CHROBACZEK, HARALD</au><format>patent</format><genre>patent</genre><ristype>GEN</ristype><title>Silanes and polysiloxanes</title><date>2009-09-23</date><risdate>2009</risdate><abstract>Monomeric silane compound (XXXV) obtained by reacting a silane compound (II) with a polyether amine compound (III), or a compound (T), which is e.g. 3-morpholin-4-yl-propylamine or 3-(2-aminoethyl)-aminopropyl-methyl-silsesquioxane with terminal methoxy group, is new. Monomeric silane compound of formula ((RO) 2-Si(R 20>)(R 1>)) (XXXV) obtained by reacting a silane compound of formula (II) with a polyether amine compound (III) of formula (CH 3-(O-CH 2-CH 2) k-(O-CH 2-CH(CH 3) l-NH 2)), or (NH 2-(CH(CH 3)-CH 2-O) l-CH 2-CH(CH 3)-NH 2) or H 2N-CH(CH 3)-CH 2-(O-CH 2-CH(CH 3) l-(O-CH 2-CH 2) k-(O-CH 2-CH(CH 3)) l-NH 2, or NH 2-CH(CH 3)-CH 2-(O-CH(CH 3)-CH 2) w-O-CH 2-C-(CH 2-O-(CH 2-CH(CH 3)-O) w-CH 2-CH(CH 3)-NH 2) 3, or a compound (T), which is 3-morpholin-4-yl-propylamine, H 2N-CH 2-CH 2-CH 2-Si(CH 3)-(O-Si(CH 3) 3) 2, HO-(CH 2-CH 2-O) k-((CH(R 3>)) 2-O) l-CH 2-CH 2-CH 2-Si(CH 3)-(O-Si(CH 3) 3)) 2or 3-(2-aminoethyl)-aminopropyl-methyl-silsesquioxane with terminal methoxy group, is new. R : phenyl residue or 1-18C-alkyl, preferably CH 3or CH 2-CH 3; R 1>R, OR or methyl-phenyl-amine moiety; R 20>-R 21>-NH-(CH 2) 2-C(=O)-O-R 22>-O-C(=O)-(CH 2) 2-NH-R 21>-Si(OR) 2(R 1>) (XXXVI), -R 21>-NH-(CH 2) 2-C(=O)-O-R 23>(XXXVII), -R 21>-NH-(CH 2) 2-C(=O)-O-(CH 2-CH 2-O) k-(CH(R 3>)-CH(R 3>)-O) l-R23a) (XXXVIII), -R 22>-NH-(CH 2) 2-C(=O)-N(R 24>) 2(XXXIX), -R21a-CH(OH)-CH 2-NH-R21a-NH-CH 2-CH(OH)-R21a-Si(OR) 2(R 1>) (XL), silane substituted cyclohexane group of formula (XL1), -R 21>-NH-C(=O)-O-CH 2-CH(R)-OH (XL1a), -R 21>-NH-C(=O)-O-CH(R)-CH 2-OH (XL1b), -R 21>-NH-CH 2-CH(R)-OH (XL1c), -R 21>-NH-CH(R)-CH 2-OH (XL1d), -R 21>-NH-C(=O)-O-CH 2-CH(R)-O-C(=O)-CH=CH 2(XL1e), -R 21>-NH-C(=O)-O-CH(R) -CH 2-O-C(=O)-CH=CH 2(XL1f), -R 21>-NH-CH 2-CH(R)-O-C(=O)-CH=CH 2(XL1g) or -R 21>-NH-CH(R)-CH 2-C(=O)-CH=CH 2(XL1h); R 21>3-8C-alkylene (which is interrupted by one or more NH-bonds), or formula (i); R21a : R 21>or a bivalent residue of formula -CH 2-CH 2-NH-CH 2-CH(CH 3)-CH 2-Si(CH 3) 2-O-Si(CH 3) 2-CH 2-CH(CH 3)-CH 2-NH-CH 2-CH 2-; R 22>6-18C-alkylene, -CH 2-CH 2-O-C(=O)-NH-R 21>-NH-C(=O)-O-R 21>-O-C(=O)-NH-R 21>-NH-C(=O)-O-CH 2-CH 2-, or -CH 2-CH 2-O-C(=O)-(CH 2) 5-O-C(=O)-NH-R 21>-NH-C(=O)-O-CH 2-CH 2-; R 23>8-16C-alkyl, -(CH 2-CH 2-O-), or -(CH(R 3>)-CH(R 3>)-O-); R23a : 8-16C-alkyl or H; R 3>H or CH 3; either k, l : 1-22; or k+l : 3-25; R 24>1-6C-alkyl; x : 0-1500, preferably 10-1500; and w : 2-8. An independent claim is included for a polyorganosiloxane compound obtained by reacting polyorganosiloxane compound of formula ((R 7>)(R) 2-Si-O-(Si(R)(R 6>)-O) x-Si(R) 2(R 7>)) (VIII) or its mixture with (XXXV) or a silane compound of formula (Si(OR) 2(R 1>)(R 2>)) (I). R 6>R or -(O-Si(R) 2) y-O-Si(R) 2-R 7>(IX); y : 0-500; R 7>R, OH or OR; R 2>vinyl residue, 1-18C-alkyl (which is optionally substituted by one or more quaternary amino-, amido-, mercapto-, epoxy-, phosphono- group, OH or F), -R 4>-O-CH 2-CH(O-R 5>)-CH 2-O-R 5>, -R 4>-NH-C(=O)-(CH 2) 3-O-C(=O)-C(R 3>)=CH 2, -R 4>-NH-((CH 2) 2-NH) p-C(=O)-(CH 2) 3-O-C(=O)-C(R 3>)=CH 2, -R 4>-O-C(=O)-C(R 3>)=CH 2, -(CH 2) 3-O-CH 2-C(R)-(CH 2-O-C(=O)-C(R 3>)=CH 2) 2, -R 4>-NH-CH(R 9>)-CH(R 3>)-COOR 8>, -R 4>-NH-CH 2-CH 2-NH-CH(R 9>)-CH(R 3>)-COOR 8>, -R 4>-R 10>-R 4>-Si(OR) 2(R 1>), -R 4>-(NH-CH 2-CH 2) p-NH-(CH(R 3>)) 2-C(=O)-N(R) 2, -R 4>-(NH-CH 2-CH 2) p-NH-(CH(R 3>)) 2-C(=O)-O-R 14>, -R 4>-(NH-CH 2-CH 2) p-NH-C(=O)-CH 2-CH 2-CH 2-OH, methyl-phenyl-amine moiety, -R 4>-(N(R 16>)-CH 2-CH 2) p-N(R 16>)-(C(=O)-O) f-CH(R)-CH 2-OH, -R 4>-(N(R 16>)-CH 2-CH 2) p-N(R 16>)-(C(=O)-O) f-CH(R)-CH 2-O-C(=O)-CH=CH 2, -R 4>-O-CH 2-CH(OH)-CH 2-NH-(CH 2-CH 2-O) u-A-((CH(R 3>)) 2-O-) v-R 17>, -R 4>-O-CH 2-CH(OH)-CH 2-N(R 13>)-(CH 2) 3-M, hydroxyl group substituted cyclohexane group of formula (XVIIIa), -R 4>-O-CH 2-CH(OH)-CH 2-O-(CH 2-CH 2-O) k-((CH(R 3>)) 2-O) l-(CH 2) 3-Si((O-Si(CH 3) 3) 2(CH 3), -R 4>-(NH-CH 2-CH 2) p-NH-CH 2-CH(OH)-CH 2-RF, -R 4>-(NH-CH 2-CH 2) p-NH-CH(CH 2OH)-RF, -R 4>-(NH-CH 2-CH 2) p-NH-CH 2-CH(OH)-CH 2-O-C(=O)-C(R 3>)=CH 2or -R 4>-(NH-CH 2-CH 2) p-NH-CH 2-CH(OH)-CH 2-NR 2>; A : a direct bond or a divalent residue of formula -CH 2-C(R 12>)(CH 2-O-(CH(R 3>)) 2-O) s-R 17>)-CH 2-O-; R 5>(-C(=O)-C(R 3>)=CH 2) or H; p : 0-2; R 4>a bivalent 1-4C-hydrocarbon; R 8>H, CH 3, C 2H 5or CH 2CH 2-OH; R 9>H or COOR 8>; R 14>H, 1-18C-alkyl or -R 4>-O-CH 2-CH(OH)-CH 2-O-(CH 2-CH 2-O) k-((CH(R 3>)) 2-O) l-(CH 2) 3-Si(OSi(CH 3) 3) 2(CH 3) (where the single units -(CH 2-CH 2-O)- and -(CHR 3>-CHR 3>-O)-); f : 0 or 1; R 16>H, -(C(=O)-O) f-CH(R)-CH 2-OH or -(C(=O)-O) f-CH(R)-CH 2-O-C(=O)-CH=CH 2; u, v, s : a value, which makes the equivalent weight of the residue R 2>of 100-5000, where one or two of u, v and s is 0; R 12>H or C 2H 5; R 17>R, -R 4>-NH 2or -CH 2-CH(CH 3)-NH-CH 2-CH(OH)-CH 2-O-R 4>-Si(OR) 2(R 1>); M : OR, N(R) 2, morpholine or -Si(CH 3)-(OSi(CH 3) 3) 2; RF : 5-23C-perfluoroalkyl; R 10>a divalent residue of formula -O-CH 2-CH(OH)-CH 2-N(R 13>)-R 11>-N(R 13>)-CH 2-CH(OH)-CH 2-O-, hydroxyl group substituted cyclohexane group of formula (XXII), -(NH-CH 2-CH 2) p-NH-(CH(R 3>)) 2-C(=O)-O-K 1>-O-C(=O)-(CH(R 3>)) 2-NH-(CH 2-CH 2-NH) p-, amide substituted cyclohexane group of formula (XXIV), or substituted benzene group of formula (XXIVa), -(CH 2) 2-NH-(CH 2) 2-, piperazine group of formula (XXVI), bis-methyl-benzen-1,4-yl, 1-chloro-4-[(4-chlorophenyl)methyl]benzene, methyl-1,3,3-trimethyl-cyclohexan-1,5-yl, -(CH 2) 2-NH-R 4>-(Si(R) 2-O) z-Si(R) 2-R 4>-NH-(CH 2) 2or -R 4>-(Si(R) 2-O) z-Si(R) 2-R 4>-, where complete or a part of N in the above formula are not a part of an amide group and exists in quaternized form; z : 8-500, preferably 8-20; f : 0 or 1; K 1>2-18C-alkylene; R 11>-(CH 2) d-; d : 1-6; and R 13>H, CH(CH 3) 2or CH 2-CH(CH 3) 3. [Image] [Image] [Image] [Image] [Image] [Image].
Silane der Formel
und neue Polysiloxane werden beschrieben, wobei die Polysiloxane durch Umsetzung von Polyorganosiloxanen mit Silanen der oben angegebenen Formel oder mit Silanen der Formel
hergestellt werden können. Die so erhaltenen neuen Polysiloxane eignen sich unter anderem für die Behandlung von textilen Flächengebilden aus natürlichen oder synthetischen Fasern.</abstract><oa>free_for_read</oa></addata></record> |
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| subjects | ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM CHEMISTRY METALLURGY ORGANIC CHEMISTRY |
| title | Silanes and polysiloxanes |
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