Silanes and polysiloxanes
Monomeric silane compound (XXXV) obtained by reacting a silane compound (II) with a polyether amine compound (III), or a compound (T), which is e.g. 3-morpholin-4-yl-propylamine or 3-(2-aminoethyl)-aminopropyl-methyl-silsesquioxane with terminal methoxy group, is new. Monomeric silane compound of fo...
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Zusammenfassung: | Monomeric silane compound (XXXV) obtained by reacting a silane compound (II) with a polyether amine compound (III), or a compound (T), which is e.g. 3-morpholin-4-yl-propylamine or 3-(2-aminoethyl)-aminopropyl-methyl-silsesquioxane with terminal methoxy group, is new. Monomeric silane compound of formula ((RO) 2-Si(R 20>)(R 1>)) (XXXV) obtained by reacting a silane compound of formula (II) with a polyether amine compound (III) of formula (CH 3-(O-CH 2-CH 2) k-(O-CH 2-CH(CH 3) l-NH 2)), or (NH 2-(CH(CH 3)-CH 2-O) l-CH 2-CH(CH 3)-NH 2) or H 2N-CH(CH 3)-CH 2-(O-CH 2-CH(CH 3) l-(O-CH 2-CH 2) k-(O-CH 2-CH(CH 3)) l-NH 2, or NH 2-CH(CH 3)-CH 2-(O-CH(CH 3)-CH 2) w-O-CH 2-C-(CH 2-O-(CH 2-CH(CH 3)-O) w-CH 2-CH(CH 3)-NH 2) 3, or a compound (T), which is 3-morpholin-4-yl-propylamine, H 2N-CH 2-CH 2-CH 2-Si(CH 3)-(O-Si(CH 3) 3) 2, HO-(CH 2-CH 2-O) k-((CH(R 3>)) 2-O) l-CH 2-CH 2-CH 2-Si(CH 3)-(O-Si(CH 3) 3)) 2or 3-(2-aminoethyl)-aminopropyl-methyl-silsesquioxane with terminal methoxy group, is new. R : phenyl residue or 1-18C-alkyl, preferably CH 3or CH 2-CH 3; R 1>R, OR or methyl-phenyl-amine moiety; R 20>-R 21>-NH-(CH 2) 2-C(=O)-O-R 22>-O-C(=O)-(CH 2) 2-NH-R 21>-Si(OR) 2(R 1>) (XXXVI), -R 21>-NH-(CH 2) 2-C(=O)-O-R 23>(XXXVII), -R 21>-NH-(CH 2) 2-C(=O)-O-(CH 2-CH 2-O) k-(CH(R 3>)-CH(R 3>)-O) l-R23a) (XXXVIII), -R 22>-NH-(CH 2) 2-C(=O)-N(R 24>) 2(XXXIX), -R21a-CH(OH)-CH 2-NH-R21a-NH-CH 2-CH(OH)-R21a-Si(OR) 2(R 1>) (XL), silane substituted cyclohexane group of formula (XL1), -R 21>-NH-C(=O)-O-CH 2-CH(R)-OH (XL1a), -R 21>-NH-C(=O)-O-CH(R)-CH 2-OH (XL1b), -R 21>-NH-CH 2-CH(R)-OH (XL1c), -R 21>-NH-CH(R)-CH 2-OH (XL1d), -R 21>-NH-C(=O)-O-CH 2-CH(R)-O-C(=O)-CH=CH 2(XL1e), -R 21>-NH-C(=O)-O-CH(R) -CH 2-O-C(=O)-CH=CH 2(XL1f), -R 21>-NH-CH 2-CH(R)-O-C(=O)-CH=CH 2(XL1g) or -R 21>-NH-CH(R)-CH 2-C(=O)-CH=CH 2(XL1h); R 21>3-8C-alkylene (which is interrupted by one or more NH-bonds), or formula (i); R21a : R 21>or a bivalent residue of formula -CH 2-CH 2-NH-CH 2-CH(CH 3)-CH 2-Si(CH 3) 2-O-Si(CH 3) 2-CH 2-CH(CH 3)-CH 2-NH-CH 2-CH 2-; R 22>6-18C-alkylene, -CH 2-CH 2-O-C(=O)-NH-R 21>-NH-C(=O)-O-R 21>-O-C(=O)-NH-R 21>-NH-C(=O)-O-CH 2-CH 2-, or -CH 2-CH 2-O-C(=O)-(CH 2) 5-O-C(=O)-NH-R 21>-NH-C(=O)-O-CH 2-CH 2-; R 23>8-16C-alkyl, -(CH 2-CH 2-O-), or -(CH(R 3>)-CH(R 3>)-O-); R23a : 8-16C-alkyl or H; R 3>H or CH 3; either k, l : 1-22; or k+l : 3-25; R 24>1-6C-alkyl; x : 0-1500, preferably 10-1500; and w : 2-8. An independent claim is included for a polyorganosiloxane compound obtained by rea |
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