OLIGOMERIZATION PROCESS

Alkenes, such as normal butenes in a mixed C4 stream are oligomerized, preferably to dimers, which are dimerized in a distillation column reactor over ZSM-57 zeolite catalyst at high conversions and high selectivity to octenes. Prior to oligomerization the mixed C4 stream is pretreated to remove dim...

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Hauptverfasser: KEENAN, MICHAEL, J, WOODS, DAVID, G, SILVERBERG, STEVEN, E, ALLEN, PAUL, W, LOESCHER, MITCHELL, E
Format: Patent
Sprache:eng ; fre ; ger
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Zusammenfassung:Alkenes, such as normal butenes in a mixed C4 stream are oligomerized, preferably to dimers, which are dimerized in a distillation column reactor over ZSM-57 zeolite catalyst at high conversions and high selectivity to octenes. Prior to oligomerization the mixed C4 stream is pretreated to remove dimethyl ether, butadienes and sulfur compounds.