ENZYMATIC PRODUCTION OF (METH)ACRYLIC ACID ESTERS

Preparing partial (meth)acrylic esters of dihydric polyalcohols (C) containing different hydroxyl groups comprising subjecting alternatively polyalcohols having primary hydroxyl group(s) and/or secondary hydroxyl group(s) and/or tertiary hydroxyl group to esterification with (meth)acrylic acid or to...

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Bibliographische Detailangaben
Hauptverfasser:	HAUER, Bernhard, MEISENBURG, Uwe, HÄRING, Dietmar
Format:	Patent
Sprache:	eng ; fre ; ger
Schlagworte:	ACYCLIC OR CARBOCYCLIC COMPOUNDS ADHESIVES BEER BIOCHEMISTRY CHEMICAL PAINT OR INK REMOVERS CHEMISTRY COATING COMPOSITIONS, e.g. PAINTS, VARNISHES ORLACQUERS COMPOSITIONS BASED THEREON CORRECTING FLUIDS DYES ENZYMOLOGY FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIREDCHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERSFROM A RACEMIC MIXTURE FILLING PASTES INKS MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONSONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS METALLURGY MICROBIOLOGY MISCELLANEOUS APPLICATIONS OF MATERIALS MISCELLANEOUS COMPOSITIONS MUTATION OR GENETIC ENGINEERING NATURAL RESINS ORGANIC CHEMISTRY ORGANIC MACROMOLECULAR COMPOUNDS PAINTS PASTES OR SOLIDS FOR COLOURING OR PRINTING POLISHES SPIRITS THEIR PREPARATION OR CHEMICAL WORKING-UP USE OF MATERIALS THEREFOR VINEGAR WINE WOODSTAINS
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Beschreibung
Zusammenfassung:	Preparing partial (meth)acrylic esters of dihydric polyalcohols (C) containing different hydroxyl groups comprising subjecting alternatively polyalcohols having primary hydroxyl group(s) and/or secondary hydroxyl group(s) and/or tertiary hydroxyl group to esterification with (meth)acrylic acid or to transesterification with (meth)acrylic ester(s) in the presence of enzyme(s), is new. Preparation of partial (meth)acrylic esters of dihydric polyalcohols (C) containing different hydroxyl groups comprises subjecting alternatively polyalcohol (C 1) having primary hydroxyl group(s) and secondary hydroxyl group(s); or polyalcohol (C 2) having primary hydroxyl group and tertiary hydroxyl group; or polyalcohol (C 3) having secondary hydroxyl group(s) and tertiary hydroxyl group(s), the more highly substituted hydroxyl group carrying in the 0 position an alkyl, cycloalkyl, aryl or aralkyl radical; or polyalcohol (C 4) having primary hydroxyl groups, of which one carries in the beta - position alkyl, cycloalkyl, aryl, and/or aralkyl radical and carries in the beta -position no such radical, or polyalcohol (C 5) having secondary hydroxyl groups, of which one carries in the beta -position alkyl, cycloalkyl, aryl, or aralkyl radical and carries in the beta -position no such radical, to esterification with (meth)acrylic acid or to transesterification with (meth)acrylic ester(s) in the presence of enzyme(s). Independent claims are also included for: (1) a partial (meth)acrylic ester of dihydric polyalcohol containing different hydroxyl groups; and (2) a thermally curable, radiation-curable or dual-cure coating material comprising a partial (meth)acrylic ester.