Polyvinyl alcohol based polymer and method of manufacturing the same

The present invention provides polyvinyl alcohol based (PVA) whose solubility in water varies with a small temperature change to a sufficiently great degree. In manufacturing a polyvinyl alcohol based polymer by: progressing a transesterification reaction of a polyvinyl ester based polymer with alco...

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Bibliographische Detailangaben
Hauptverfasser: YANAI, HISAMICHI, MIYATA, KIMIKO, FUJIWARA, NAOKI, TOKUDA, YOSHIHIRO, KUSUDOU, TAKESHI, TOKUYASU, JIN
Format: Patent
Sprache:eng ; fre ; ger
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Zusammenfassung:The present invention provides polyvinyl alcohol based (PVA) whose solubility in water varies with a small temperature change to a sufficiently great degree. In manufacturing a polyvinyl alcohol based polymer by: progressing a transesterification reaction of a polyvinyl ester based polymer with alcohol in a liquid reaction mixture including the polyvinyl ester based polymer, the alcohol, and a basic compound; precipitating the polyvinyl ester based polymer, at least a part of which has been transesterified with the alcohol, out of the liquid reaction mixture; and further progressing the transesterification reaction in the liquid reaction mixture including the polyvinyl ester based polymer that has precipitated, the liquid reaction mixture has a temperature of 75 DEG C to 150 DEG C when the polyvinyl ester based polymer, at least a part of which has been transesterified, starts precipitating.