PROTON-CONDUCTING MEMBRANE AND USE THEREOF

Proton-conducting polymer membranes based on polyazoles are obtained by making a solution or dispersion of aromatic tetra-amine and aromatic polycarboxylic acid(s) in polyphosphoric acid, coating the mixture onto a support and heating under inert gas. Proton-conducting polymer membranes based on pol...

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Bibliographische Detailangaben
Hauptverfasser:	KIEFER, JOACHIM, UENSAL, OEMER, SANSONE, MICHAEL, J, CALUNDANN, GORDON
Format:	Patent
Sprache:	eng ; fre ; ger
Schlagworte:	AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F,C08G APPLYING LIQUIDS OR OTHER FLUENT MATERIALS TO SURFACES, IN GENERAL BASIC ELECTRIC ELEMENTS CHEMISTRY COMPOSITIONS BASED THEREON COMPOSITIONS OF MACROMOLECULAR COMPOUNDS ELECTRICITY GENERAL PROCESSES OF COMPOUNDING MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONSONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS METALLURGY ORGANIC MACROMOLECULAR COMPOUNDS PERFORMING OPERATIONS PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL PROCESSES FOR APPLYING LIQUIDS OR OTHER FLUENT MATERIALS TOSURFACES, IN GENERAL PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSIONOF CHEMICAL INTO ELECTRICAL ENERGY SEPARATION SPRAYING OR ATOMISING IN GENERAL THEIR PREPARATION OR CHEMICAL WORKING-UP TRANSPORTING WORKING-UP
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Beschreibung
Zusammenfassung:	Proton-conducting polymer membranes based on polyazoles are obtained by making a solution or dispersion of aromatic tetra-amine and aromatic polycarboxylic acid(s) in polyphosphoric acid, coating the mixture onto a support and heating under inert gas. Proton-conducting polymer membranes based on polyazoles are obtained by: (A) mixing aromatic tetra-amino compounds with aromatic carboxylic acids with at least two carboxylic acid groups, or their esters, in polyphosphoric acid to form a solution and/or dispersion; (B) coating the mixture onto a support; (C) heating under inert gas at up to 350 (preferably up to 280)[deg]C, to form a polyazole; and (D) treatment to form a self-supporting membrane. Independent claims are also included for: (a) electrodes with a proton-conducting polyazole-based coating obtained by the above process; (b) membrane-electrode units containing at least one electrode and at least one membrane as described; (c) membrane-electrode units containing at least one electrode as in (a) and at least one membrane as described; and (d) fuel cells containing these membrane-electrode units.