Sensors for the determination of organometallic compounds

Sensors for the determination of organometallic compounds, e.g. n-butyllithium, comprise the following elements: a)an inorganic, organic or polymeric support, insoluble in the sample to analyze b)an indicator which reversibly reacts with the organometallic compound and whose reaction product gives a...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Hauptverfasser: ORELLANA MORALEDA, GUILLERMO, CASTRO FRANCO, ANA MARIA, FRAGA TRILLO, LUISA MARIA, RUIZ SANTA QUITERIA, VALENTIN
Format: Patent
Sprache:eng ; fre ; ger
Schlagworte:
Online-Zugang:Volltext bestellen
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:Sensors for the determination of organometallic compounds, e.g. n-butyllithium, comprise the following elements: a)an inorganic, organic or polymeric support, insoluble in the sample to analyze b)an indicator which reversibly reacts with the organometallic compound and whose reaction product gives a characteristic absorption, reflection or emission band in the range 150-15000nm, e.g. 1,10-phenanthroline and derivatives, triphenylmethane, or N-Ä2-(4-hydroxybenzyl)phenylÜ-2,2-dimethylpropanamide, and which is physically trapped, adsorbed, absorbed, dissolved or chemically linked in an electrostatic or covalent way to the support c)an optical sensor which measures the absorption, reflection or emission of the functionalized support at the characteristic wavelength and transforms it in the concentration of the organometallic present in the solution. Also described is the method for the determination of the concentration of organometallic compounds by the on line use of a sensor in anionic polymerizations.