HIGH TEMPERATURE PHA EXTRACTION USING PHA-POOR SOLVENTS
Polyhydroxyalkanoate (PHA) polyester is extracted from biomass by dissolving the PHA in a non-halogenated solvent which comprises a PHA-poor solvent that dissolves less than 1% of the PHA at temperatures less than the solvent boiling point, or a mixture of a PHA-poor solvent and a PHA-good solvent....
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Zusammenfassung: | Polyhydroxyalkanoate (PHA) polyester is extracted from biomass by dissolving the PHA in a non-halogenated solvent which comprises a PHA-poor solvent that dissolves less than 1% of the PHA at temperatures less than the solvent boiling point, or a mixture of a PHA-poor solvent and a PHA-good solvent. Following extraction of PHA under pressure at a temperature above about 80 DEG C., typically above the boiling point of the PHA-poor solvent, PHA polymer is precipitated by cooling the PHA-enriched solvent mixture. Suitable PHA-poor solvents can include linear and branched R1-OH alcohols and R2-COOR3 esters where R1=C1-C4, R2=H, C1,C2, or C3, and R3=C1-C5. |
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