Grafted polymer moulding compositons with reduced buildup

ABS-type thermoplastic moulding materials (I), containing: (A) 5-95 wt.% thermoplastic homo-, co- or ter-polymer(s) of styrene (S), alpha -methylstyrene (AMS), acrylonitrile (AN) and/or N-substituted maleimide; (B) 5-95 wt.% graft copolymer(s) of (B1) 5-90 pts. wt. monomer(s) as in (A) on (B2) 95-10...

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Bibliographische Detailangaben
Hauptverfasser: SARABI, BAHMAN, ECKEL, THOMAS, EICHENAUER, HERBERT, ALBERTS, HEINRICH, WITTMAN, DIETER, LEITZ, EDGAR
Format: Patent
Sprache:eng ; fre ; ger
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Zusammenfassung:ABS-type thermoplastic moulding materials (I), containing: (A) 5-95 wt.% thermoplastic homo-, co- or ter-polymer(s) of styrene (S), alpha -methylstyrene (AMS), acrylonitrile (AN) and/or N-substituted maleimide; (B) 5-95 wt.% graft copolymer(s) of (B1) 5-90 pts. wt. monomer(s) as in (A) on (B2) 95-10 pts. wt. rubber with a Tg of ≤ 0 degrees C; and (C) 1-10 pts. wt. (per 100 pts. wt. A + B) lubricants, antistatics and/or mould release additives. Component (A) is obtained by bulk, solution or suspension polymerisation and has an oligomer content of ≤ 1 wt.%, component (B) is obtained by emulsion polymerisation, with the total oligomer content of (I) being ≤ 0.8 wt.%, and the ratio (R) of mol. wt. of additive : wt.% of additive in (I) ≥ 150.