Catalyst systems for the polymerization and copolymerization of alpha-olefins

Catalyst component for the polymerisation of alpha-olefins of general formula (I) wherein:M is a transition metal of groups 3, 4-10, lanthanide or actinide of the periodic table of the elements; A is a ring with delocalized π electrons, L is a neutral Lewis base; m is an integer whose value can be:...

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Bibliographische Detailangaben
Hauptverfasser: MARTIN MARCOS, CARLOS, PENA GARCIA, BEGONA, MUNOZ-ESCALONA LAFUENTE, ANTONIO, SANCHO ROYO, JOSE
Format: Patent
Sprache:eng ; fre ; ger
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Zusammenfassung:Catalyst component for the polymerisation of alpha-olefins of general formula (I) wherein:M is a transition metal of groups 3, 4-10, lanthanide or actinide of the periodic table of the elements; A is a ring with delocalized π electrons, L is a neutral Lewis base; m is an integer whose value can be: 0 or 1; E is selected from the group comprising: BRII, CRII2, SiRII2, GeRII2; Hal is selected from the group comprising iodine, bromine or chlorine; RIII has the same meaning of RII; Si is a silicon atom; D is selected from the group comprising: O, S, NRIV, PRIV, ORIV, SRIV, NRIV2, PRIV2; each X group equal to or different from each other is selected from the group comprising hydrogen, halide, alkyl, cycloalkyl, aryl, alkenyl, arylalkyl, arylalkenyl or alkylaryl with 1 to 20 carbon atoms, n is a number whose value can be: 0, 1, 2 or 3, in order to full the remaining valences of metal M. It is also described a method for supporting the compound of formula I.