Production of vinylidene olefins

Production of vinylidene olefins

Production of vinylidene olefin derivs. (I) using a trialkylaluminium compound as the sole catalyst component charged to the reaction vessel, comprises dimerising vinyl olefin (VO) with at least one trialkylaluminium compound (TAC) as the catalyst in a ratio of 0.001-0.05 mole TAC per mole VO at tem...

Ausführliche Beschreibung

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Bibliographische Detailangaben
Hauptverfasser: LANIER, CARROLL W, LIN, KAUNG-FAR
Format: Patent
Sprache:eng ; fre ; ger
Schlagworte:
ACYCLIC OR CARBOCYCLIC COMPOUNDS
APPARATUS THEREFOR
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY
CHEMISTRY
GENERAL METHODS OF ORGANIC CHEMISTRY
METALLURGY
ORGANIC CHEMISTRY
PERFORMING OPERATIONS
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
THEIR RELEVANT APPARATUS
TRANSPORTING
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Beschreibung
Zusammenfassung:Production of vinylidene olefin derivs. (I) using a trialkylaluminium compound as the sole catalyst component charged to the reaction vessel, comprises dimerising vinyl olefin (VO) with at least one trialkylaluminium compound (TAC) as the catalyst in a ratio of 0.001-0.05 mole TAC per mole VO at temperature between 140-172 [deg]C for 1-24 hours to convert >= 10 wt.% VO to a different product with - 80 wt.% vinylidene dimer selectivity.