OLIGOTHIOPHENES

The invention pertains to thiophenes of the formula (I), where n is 2 to 6; L and L are hydrogen, optionally substituted C1-C10 alkyl, C3-C7 cycloalkyl or phenyl, or L and L together with the connecting nitrogen atom represent a heterocyclic radical; X and Y are hydrogen, optionally substituted C1-C...

Ausführliche Beschreibung

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Bibliographische Detailangaben
Hauptverfasser:	BECKMANN, STEFAN, STEYBE, FELIX, WUERTHNER, FRANK, ANDREAS, EFFENBERGER, FRANZ
Format:	Patent
Sprache:	eng ; fre ; ger
Schlagworte:	ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY CHEMISTRY COMPOSITIONS BASED THEREON HETEROCYCLIC COMPOUNDS MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS METALLURGY ORGANIC CHEMISTRY ORGANIC MACROMOLECULAR COMPOUNDS PERFORMING OPERATIONS PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL THEIR PREPARATION OR CHEMICAL WORKING-UP THEIR RELEVANT APPARATUS TRANSPORTING
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Beschreibung
Zusammenfassung:	The invention pertains to thiophenes of the formula (I), where n is 2 to 6; L and L are hydrogen, optionally substituted C1-C10 alkyl, C3-C7 cycloalkyl or phenyl, or L and L together with the connecting nitrogen atom represent a heterocyclic radical; X and Y are hydrogen, optionally substituted C1-C10 alkyl, C3-C7 cycloalkyl or phenyl; and Z is cyano, hydroxysulfonyl, C1-C10 alkoxycarbonyl, optionally substituted C1-C4 alkylsulfonyl, optionally substituted phenylsulfonyl or a radical of the formula (a), where R is hydrogen or cyano and R and R are cyano, nitro, C1-C10 alkoxycarbonyl, optionally substituted C1-C4 alkylsulfonyl or optionally substituted phenylsulfonyl. The invention also relates to the use of said thiophenes in nonlinear optics, a method for the preparation of bithiophenes, and stannylthiophenes as their intermediates.