Diphosphines
Diphosphine is of formula: R2-P(R3)-R4-O-A-O-R4-P(R3)-R2 (I) R2, R3 = (cyclo)alkyl or aryl(alkyl) or aryl substd. by halo, alkyl and/or alkoxy; R4 = (cyclo)alkylene, aryl(alkyl)ene or arylene substd. by halo, alkyl, and/or alkoxy; A = CO, SO2, SO-, CO-alkylene-CO or CO-arylene-CO where arylene is op...
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Sprache: | eng ; fre ; ger |
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Zusammenfassung: | Diphosphine is of formula: R2-P(R3)-R4-O-A-O-R4-P(R3)-R2 (I) R2, R3 = (cyclo)alkyl or aryl(alkyl) or aryl substd. by halo, alkyl and/or alkoxy; R4 = (cyclo)alkylene, aryl(alkyl)ene or arylene substd. by halo, alkyl, and/or alkoxy; A = CO, SO2, SO-, CO-alkylene-CO or CO-arylene-CO where arylene is opt. substd. by halo, (cyclo)alkyl, aryl, oxyalkyl, OH, alkoxy and/or CO-(O-R4-PR2R3), and alkylene is opt. substd. by halo, (cyclo)alkyl, aryl, oxyalkyl, OH, alkoxy and/or CO-(CO-R4-PR2R3); or A = P(O)(O-R4-PR2R3), P(O)(R6), Si(R7)(R8), Si(R9)(O-R4-PR2R3) or Si(O-R4-PR2R3)2; and R6-R9 = (cyclo)alkyl, aryl (alkyl) or aryl substd. by halo, (cyclo)alkyl, aryl, oxyalkyl, OH or alkyl. Also claimed are: (a) the prepn. of the above polymer, (b) a polymer compsn. stabilised by the polymer, and (c) a method of stabilising a polymer compsn. |
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