Oligomeric HALS-phosphites and HALS-phosphonites as stabilizers

Oligomeric cpds. of formula (I) are claimed, where L is -O-R2-O- or -NR4-X-R3-O-; R1 is a 1-25C alkyl, 2-25C alkyl with in-chain O, S or >NR5, 2-24C alkenyl, 5-15C cycloalk(en)yl (opt. substd. with 1-4C alkyl), 7-9C phenylalkyl (opt. ring-substd. with 1-4C alkyl) tetrahydroabietyl, etc.; R2 is e....

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Bibliographische Detailangaben
1. Verfasser:	PITTELOUD, RITA
Format:	Patent
Sprache:	eng ; fre ; ger
Schlagworte:	ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBONFILAMENTS CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS,THREADS, FIBRES, BRISTLES OR RIBBONS CHEMISTRY COMPOSITIONS BASED THEREON COMPOSITIONS OF MACROMOLECULAR COMPOUNDS MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONSONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS METALLURGY NATURAL OR ARTIFICIAL THREADS OR FIBRES ORGANIC CHEMISTRY ORGANIC MACROMOLECULAR COMPOUNDS SPINNING TEXTILES THEIR PREPARATION OR CHEMICAL WORKING-UP USE OF INORGANIC OR NON-MACROMOLECULAR ORGANIC SUBSTANCES ASCOMPOUNDING INGREDIENTS
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Beschreibung
Zusammenfassung:	Oligomeric cpds. of formula (I) are claimed, where L is -O-R2-O- or -NR4-X-R3-O-; R1 is a 1-25C alkyl, 2-25C alkyl with in-chain O, S or >NR5, 2-24C alkenyl, 5-15C cycloalk(en)yl (opt. substd. with 1-4C alkyl), 7-9C phenylalkyl (opt. ring-substd. with 1-4C alkyl) tetrahydroabietyl, etc.; R2 is e.g. -R3-N(Y)-R3-;Y is a gp. of formula (iii); R3 is a 1-18C alkylene, 2-18C alkylene with in-chain O, S or >NR5, 4-8C alkenylene or phenylethylene; R4 is a 1-8C alkyl or gp. of formula (iii); R5 is H or 1-8C alkyl; R10 is H, 1-8C alkyl, O, OH, NO, CH2CN, 1-18C alkoxy, 5-12C cycloalkoxy, 3-6C alkenyl, or alkynyl, 1-8C acyl or 7-9C phenylalkyl (opt. ring substd. with 1-4C alkyl); m = 0 or 1; and n = 2-25. Also claimed are (a) a process for the prodn. of (I) by reacting cpds. of formula R1-(O)m-PCl2, (XXII) with cpds. of formula H-L-H (XXIII); (b) oligomeric cpds. obtd. by the process; (c) compsns. (A) contg. (1) organic material which is subject to oxidative, thermal or light induced degradation, and (2) cpd(s). (I) or the oligomeric prod(s).; and (d) a process for stabilising organic materials, against degradation as above, by mixing or coating the material with (I).