Bulk polymerization of norbornene derivatives
A process for the bulk polymerization of norbornene derivatives which comprises contacting a norbornene derivative with a catalyst system which may be prepared by combining a) a tungsten compound catalyst component obtainable by combining a tungsten oxytetrahalide and a substituted phenol having at...
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Format: | Patent |
Sprache: | eng ; fre ; ger |
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Zusammenfassung: | A process for the bulk polymerization of norbornene derivatives which comprises contacting a norbornene derivative with a catalyst system which may be prepared by combining a) a tungsten compound catalyst component obtainable by combining a tungsten oxytetrahalide and a substituted phenol having at least one bulky alkyl substituent, containing at least 3 carbon atoms, on the aromatic ringstructure in a position which is ortho with respect to the hydroxyl group, and b) at least a tin hydride of general formula (R R R )SnH, wherein R and R each may represent hydrogen or may have the meaning of R , representing an optionally substituted alkyl group having in the range of from 1 to 20 carbon atoms, an optionally substituted cycloalkyl group having in the range of from 3 to 6 carbon atoms in the cycloalkyl ring or an optionally substituted phenyl group. |
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