Bulk polymerization of norbornene derivatives

A process for the bulk polymerization of norbornene derivatives which comprises contacting a norbornene derivative with a catalyst system which may be prepared by combining a) a tungsten compound catalyst component obtainable by combining a tungsten oxytetrahalide and a substituted phenol having at...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Hauptverfasser: SJARDIJN, WILLEM, VAN DER LINDEN-LEMMERS, WILHELMINA JOHANNA MARIA, SEELEN-KRUIJSSEN, JOSEPHA MARIA ELISABETH
Format: Patent
Sprache:eng ; fre ; ger
Schlagworte:
Online-Zugang:Volltext bestellen
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:A process for the bulk polymerization of norbornene derivatives which comprises contacting a norbornene derivative with a catalyst system which may be prepared by combining a) a tungsten compound catalyst component obtainable by combining a tungsten oxytetrahalide and a substituted phenol having at least one bulky alkyl substituent, containing at least 3 carbon atoms, on the aromatic ringstructure in a position which is ortho with respect to the hydroxyl group, and b) at least a tin hydride of general formula (R R R )SnH, wherein R and R each may represent hydrogen or may have the meaning of R , representing an optionally substituted alkyl group having in the range of from 1 to 20 carbon atoms, an optionally substituted cycloalkyl group having in the range of from 3 to 6 carbon atoms in the cycloalkyl ring or an optionally substituted phenyl group.