Epoxy-functionalized polyphenylene ethers

Epoxy-functionalized polyphenylene ethers are prepared by melt blending a polyphenylene ether with glycidyl acrylate in the presence of a lubricant such as at least one hydrogenated poly- alpha -olefin. The blending reaction takes place at a temperature in the range of about 250-300 DEG C, and the a...

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Bibliographische Detailangaben
Hauptverfasser:	YATES III, JOHN BENNIE, KHOURI, FARID FOUAD, HALLEY, ROBERT JAMES
Format:	Patent
Sprache:	eng ; fre ; ger
Schlagworte:	CHEMISTRY COMPOSITIONS BASED THEREON COMPOSITIONS OF MACROMOLECULAR COMPOUNDS GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONSONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS METALLURGY ORGANIC MACROMOLECULAR COMPOUNDS TECHNICAL SUBJECTS COVERED BY FORMER USPC TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ARTCOLLECTIONS [XRACs] AND DIGESTS THEIR PREPARATION OR CHEMICAL WORKING-UP
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Beschreibung
Zusammenfassung:	Epoxy-functionalized polyphenylene ethers are prepared by melt blending a polyphenylene ether with glycidyl acrylate in the presence of a lubricant such as at least one hydrogenated poly- alpha -olefin. The blending reaction takes place at a temperature in the range of about 250-300 DEG C, and the amount of glycidyl acrylate employed is about 2.5-5.0% by weight based on polyphenylene ether. The products are characterized by a gel content of less than 5% by weight. They form copolymer-containing compositions having excellent properties upon melt blending with linear polyesters such as poly(butylene terephthalate).