Use of helium and argon diluent gases in modification of carbon molecular sieves

Carbon molecular sieves, useful in the separation of air into oxygen and nitrogen, are improved through modification of the micropores of the sieve by contact with the pyrolysis products of a carbon-containing compound in the gaseous state diluted with helium, with or without nitrogen as a part of t...

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Hauptverfasser: ARMOR, JOHN NELSON, GAFFNEY, THOMAS RICHARD, BRAYMER, THOMAS A, FARRIS, THOMAS STEPHEN
Format: Patent
Sprache:eng ; fre ; ger
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Zusammenfassung:Carbon molecular sieves, useful in the separation of air into oxygen and nitrogen, are improved through modification of the micropores of the sieve by contact with the pyrolysis products of a carbon-containing compound in the gaseous state diluted with helium, with or without nitrogen as a part of the diluting gas. Volatile organic compounds, such as trimethylcyclohexane, are used with the diluent gas to narrow the micropore openings of a carbon molecular sieve and increase its kinetic selectivity for oxygen adsorption. Carbon dioxide and helium or argon in the diluent gas are used to open pores available to contacting gases.