Halocarbon hydrogenolysis

Halocarbons such as CCl2F2, CF3CFHCl or CF3CFCl2 which contain chlorine and/or bromine are contacted with hydrogen in the presence of silicon carbide and/or a metal selected from aluminum, molybdenum, titanium, nickel, iron or cobalt (or their alloys) at temperatures of 350 DEG to 700 DEG C and pres...

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Bibliographische Detailangaben
Hauptverfasser: KIELHORN, FERNANDO, FREDERICK, RAO, V., N., MALLIKARJUNA, MANOGUE, WILLIAM, HENRY
Format: Patent
Sprache:eng ; fre ; ger
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Zusammenfassung:Halocarbons such as CCl2F2, CF3CFHCl or CF3CFCl2 which contain chlorine and/or bromine are contacted with hydrogen in the presence of silicon carbide and/or a metal selected from aluminum, molybdenum, titanium, nickel, iron or cobalt (or their alloys) at temperatures of 350 DEG to 700 DEG C and pressures of 0 to 1000 psig to obtain a product wherein at least one chlorine or bromine in the starting material has been replaced by hydrogen.