METHOD FOR THE PRODUCTION OF ALPHA,BETA-UNSATURATED CARBONYL COMPOUNDS
Method for the production of alpha ,ss-unsaturated carbonyl compounds of the general formula I in which R is hydrogen, C1- to C10-alkyl, C1- to C10-alkoxy or aryloxy, R is aryl which is optionally substituted by C1- to C4-alkyl, C1- to C4-alkoxy, trifluoromethyl and/or halogen and R is tetrahy...
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Hauptverfasser: | , , |
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Format: | Patent |
Sprache: | eng ; ger |
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Zusammenfassung: | Method for the production of alpha ,ss-unsaturated carbonyl compounds of the general formula I
in which
R is hydrogen, C1- to C10-alkyl, C1- to C10-alkoxy or aryloxy,
R is aryl which is optionally substituted by C1- to C4-alkyl, C1- to C4-alkoxy, trifluoromethyl and/or halogen and
R is tetrahydrofuranyl, or aryl which is substituted by C1- to C4-alkyl, C1- to C4-alkoxy, trifluoromethyl and/or halogen,
characterised in that 3-aminoprop-2-en-1-ones of the general formula II
in which
R and R have the abovementioned meanings and
R and R independently of one another are hydrogen, C1- to C10-alkyl or aryl,
are reacted with a magnesium halide of the general formula III
R -Mg-Y (III),
in which Y represents halogen, at temperatures of -20 to 100 DEG C, and novel alpha ,ss-unsaturated carbonyl compounds, and novel 3-aminoprop- 2-en-1-ones. |
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